生物质气化再燃技术中焦油的利用-中国电机工程学报.PDF

第 30 卷 第 17 期 中 国 电 机 工 程 学 报 Vol.30 No.17 Jun.15, 2010 98 2010 年 6 月 15 日 Proceedings of the CSEE ©2010 Chin.Soc.for Elec.Eng. 0258-8013 (2010) 17-0098-06 TK 6 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 生物质气化再燃技术中焦油的利用 张睿智，罗永浩，刘春元，段佳 (上海交通大学机械与动力工程学院，上海市 闵行区 200240) Utilization of Tar in Biomass Gasification Reburning Process ZHANG Rui-zhi, LUO Yong-hao, LIU Chun-yuan, DUAN Jia (School of Mechanical Engineering, Shanghai Jiao Tong University, Minhang District, Shanghai 200240, China) ABSTRACT: The utilization of tar in the process of biomass 组分还原 NO 存在最佳的当量比，并要求合适的温度窗口， gasification reburning was investigated. The tar components 需要关注聚合反应；甲苯还原 NO 机制(NO reduction by released during the pyrolysis and gasification of typical toluene ，NRT)模型与实验结果拟合良好，模型的生成速率 agricultural wastes were analyzed on the TG-MS 和消耗速率分析显示 HCCO 和 C2H 在焦油还原 NO 中具有 (thermogravimetry and mass spectrometry) system. And the 重要作用。 effect of tar on the NO reduction by biomass gasification 关键词：生物质；气化；再燃；焦油；模型化合物；机制 syngas was studied on a flow reaction system, as well as the 模型 effect of the parameters such as bulk equivalence ratio and temperature. Finally, the model of NO reduction by toluene 0 引言 was built, and verified by the results from the stop-flow 化石能源日益枯竭，环境污染日益严重，对于 reaction system. The results show that benzene, toluene, 拥有大量燃煤电站锅炉、工业锅炉的中国，发展的 styrene and phenol are typical components of tar. Tar