烃类加氢异构化及加氢异构裂化催化剂的研究开发-中国科学院大连.PDF

第 30 卷 第 8 期 催 化 学 报 2009 年 8 月 Vol. 30 No. 8 Chinese Journal of Catalysis August 2009 文章编号: 0253-9837(2009)08-0705-06 综述: 705~710 烃类加氢异构化及加氢异构裂化催化剂的研究开发 田志坚, 梁东白, 林励吾 中国科学院大连化学物理研究所, 辽宁大连 116023 摘要：综述了中国科学院大连化学物理研究所烷烃加氢异构化和加氢异构裂化反应催化剂的研发历程、工业应用及对我国石 油炼制工业所做的贡献. 1960 年代, 大连化学物理研究所在烷烃加氢异构化的研究中提出了“ 电子-酸性催化剂杂交规律”, 并相 继成功研发石蜡基重油加氢异构裂化催化剂和重油单段加氢异构裂化催化剂, 并应用于从大庆石蜡基原油馏分生产低冰点航 空煤油. 重油单段加氢异构裂化催化剂在大庆炼油厂建成的 40 万吨/年加氢异构裂化装置工业应用已 20 多年, 创造了巨大的经 济和社会效益. 进入 21 世纪, 大连化学物理研究所又开发出了以分子筛为载体的润滑油基础油加氢异构脱蜡催化剂, 于 2008 年 在中国石油大庆炼化公司建成 20 万吨/年的工业装置实现工业化应用. 关键词：加氢裂化; 加氢异构化; 双功能催化剂 中图分类号：O643 文献标识码：A Research and Development of Hydroisomerization and Hydrocracking Catalysts In Dalian Institute of Chemical Physics * TIAN Zhijian , LIANG Dongbai, LIN Liwu Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China Abstract: The research and development of catalysts and catalytic processes for hydroisomerization and hydrocracking of petroleum feed- stocks in Dalian Institute of Chemical Physics (DICP) are described. In the 1960s, on the basis of extensive investigations, DICP researchers summarized a series of rules for governing the preparation of hydroisomerization and hydrocracking catalysts. By utilizing these rules as guidelines, DICP investigators have developed hydrocracking catalysts suitable for use in a single-stage process of vacuum gas oil hydro- cracking. The catalysts as well as the process were then commercialized successfully in the first hydrocracking unit of China, which was constructed