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在此输入标题 副标题 Introduction Experimental Results and discussion Conclusion Introduction Chitin (poly-β-(1,4)-N-acetyl-d-glucosamine) is the second most abundant natural biopolymer after cellulose and a basic structural component of fungi and yeast cell walls, as well as of numerous invertebrates. 自然界中含量仅次于纤维素的一种天然高聚物 The chitin-based scaffolds recently found by our groups in marine sponges are three-dimensional networks of tube-like interconnected fibers with a diameter of about 100 μm in the case of Aplysina aerophoba . 支架是通过直径约100μm的管状纤维连接形成的三维网络 The adsorption behavior was tested in lifelike concentration ranges.We further attempted to desorb the uranyl in order to recover the sponge chitin and make it reusable. The kinetics of the adsorption process were examined to determine the time needed for the adsorption. The interaction mechanisms between chitin and uranyl were examined with solid-state NMR, infrared, Raman as well as time-resolved laser fluorescence spectroscopy. Experimental Marine sponge Aplysina aerophoba :collected in the Adriatic Sea (Kotor Bay, Montenegro) and dried on air. NaOH platelets :purchased from Grüssing (99%). Concentrated acetic acid : purchased from VWR (HPLC grade). α-Chitin : purchased from Carl Roth GmbH(depure). NaClO4·2H2O, NaOH and HCl : purchased from Merck (analytical grade). Concentrated HNO3 : purchased from Carl Roth GmbH (analytical grade) and distilled before usage. A 1000 mg/l rhodium solution :purchased from Merck (ICP-MS standard). UO2(ClO4)2 :0.102 M Ionic strength:0.5 M (NaClO4) Results and discussion The sponge chitin is completely acetylated within the limits of experimental error.(甲基的相对强度为103%) The extracted fibers consist of concentrically arranged and loosely packed tubular structures with hollow spaces in between. (由松散的同心排列的管状结构组成)
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