渗碳的传质的数学模型及意义-重庆大学学报.PDF

1 989年 9月 重 庆 大 学 学 报 V01．12．No．5 JOURNAL OF CHONGQING UNIVERSITY Sept．1989 第12卷第 5期 渗碳 的传质 的数学模型及 意义 THE MATHEMATtCAL MODEL OF CARBURIZED MASS-TRANSFER AND iTS MEANINGS 张 T 非 晃 恩 椿 Zhang Dingfel Wh Enling (重庆大学； 金系) (浙江太学材料摹) 摘 要 本文研究了气体渗碳过程中，碳原子由气相到固相传递的动力学 报 据固相表面的化学反应动力学方程，推导出碳由气相到固相的传递量正比于气一固 相问碳的活度差。由此建立气一固相碳传递的动力学方程，并讨论了碳传递速度的 影响团素 可推知，增加气相中一氧化碳和氢气含量可提高碳传递速度，另外，适 量氧化介质特{；4是水可加速碳的传递。 关键饲 渗碳 传质 活度，动力学 一 中国图书资料分类法分类号 TG 151．5，TG 151．81 ABSTRACT This paper deals with the kinetics of carbon atoms transfer from gas phase to solid phase in gas carburlzing According to the kinetic - ． equations of the chemical reactions on the solid surface．it is deduced that the carbon transfer quantity from gas phase to solid phase is in direct proper· tion to the difference of carbon activities between gas phase and solid pha se ． Based 011 what is mentioned above，we set up the kinetic equation of carbon transfer from gas phase to solid phase，discu ssed the factors which affected the carbon transfer It was known then that increasing the contents of carbon ． monoxide and hydrogen in gas phase eou[d quicken the carbon transfer On the ． other hand，proper oxidants，especially proper water，could quicken the carbon transfer． KEY WORDS carburizingJ mass·transfer|activityI kinetics 本文于l988年 4月4日收到。