焦炉煤气制氢的流程改进与技术经济性能预报-NSFC.PDF

第31 卷 第0 期 中 国 电 机 工 程 学 报 Vol.31 No.0 000.00, 2011 2011 年0 月00 日 Proceedings of the CSEE ©2011 Chin.Soc.for Elec.Eng. 1 0258-8013 (2011) 00-0000-00 TK16 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 焦炉煤气制氢的流程改进与技术经济性能预报 王逊 ( 中国科学院工程热物理研究所，北京市 海淀区 100190) Process Innovation of Coke Oven Gas to Hydrogen System and Technical-economic Performance Prediction XUN Wang (Institute of Engineering Thermophysics, Chinese Academy of Sciences, Haidian District, Beijing 100190, China) ABSTRACT: According to the unit characteristics and the 关键词：CO2 吸收增强制氢；焦炉煤气能量转化效率；氢 relationships of mass and energy, alternative procedures to 气产率；流程改进；动态投资回收期 produce hydrogen from coke oven gas (COG) were proposed. 0 引言 In these hydrogen amplification systems, CO2 adsorption enhanced hydrogen reactor was combined with pressure swing 焦炉煤气含有50% 以上的氢气，采用变压吸附 adsorption (PSA) separation process. Their performances were 技术(pressure swing adsorption，PSA)从中提取高纯 analyzed and evaluated by technical and economic indicators 度氢气已成为焦炉煤气利用的重要途径。PSA 制氢 which include energy conversion efficiency, hydrogen yield per 可获得较高的氢浓度和氢气回收率，在国内多家钢 unit COG and dynamic payback period. Comparisons with PSA 厂得到应用，取得了很好的技术经济效益。对PSA separation and hydrogen amplification system with steam 分离解吸气中的甲烷、CO、未回收氢等组分一般采 reformer were also investigated. Simulation results indicates 用送入煤气管网、燃烧利用发电[1-2]、生产代天然 that hydrogen amplifi