金属离子掺杂稀土氧化物的制备及其发光性能研究-物理学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 Abs仃 Abs仃act Abstract With the rapid development of luminescence materials in these recent years，as well as the growing requirement of these materials in real—life situations，both fluorescent membrane and phosphors have been research focuses，and aroused extensive concern in recent years． In the current master dissertation，three major topics have been involved．Firstly， the Yo．5-xGao．35Euo．15BixNb04(Ox-O．30) and Yo．35Gd0．35Euo．15Bio．15Nbl-yPy04 (0句s0．20)phosphors have been synthesized by the conventional solid-state reaction． As for these Y0．5-xGd0．35Euo．15BixNb04(0sx≤0．30)samples，with increasing Bi content， the emission firstly increases and then decreases．Therefore，the maximum emission is achieved when X is 0．1 8．This tendency is closely related to the following two factors． One is the energy transfer process between Bi3+ions and Eu3+ions，the other is related to the distortion of the crystal field surrounding Eu3+ions．About those Y0．35Gdo．35Euo．1sBio．1sNbl．yPy04(0Sy≤0．20)samples，the emission and excitation intensities are botll varied with the P doping content．The strongest intensity is obtained in the case of Y=O．1 5．This is also ascribed to the following two factors． One is the increasing absorption of V043。with the increase of the P5+content，and the other is the nephelauxetic effect which may also influence on the Eu3+emission intensity．Our obtained results suggest that the Bi dopant acts as one sensitizer and eventually enhances the photoluminescence intensity．The introduction of P043。also plays an important role in the photoluminescence properties of the investigated samples．Secondly，Y203：Eu3+(5％)，Li+(x％)phosphor thin film has been prepared by electro-deposited method．The XRD data show that the doped Li+ions do not change the structure of Y203：Eu”．SEM results suggest that the samples are composed of a large number of uniform nano-structure flakes．With Li doping，the flakes aggregate gradually and the flower-like micro—architectures are observ