金属缓蚀剂的制备及对水性环氧涂料性能的促进作用-高分子化学与物理专业论文.docxVIP

优秀毕业论文 精品参考文献资料 ABSTRACTThis ABSTRACT This paper studied two corrosion inhibitors aniline trimers口乃and epoxy Phosphate(HEP)for carbon steel corrosion resistance and their application in aqueous epoxy resin．Specific research contents and results are as follows： 1、Aniline trimer 0乃was prepared by chemical oxidation which is an inhibitor containing three N AToms．FTIR，UV-visible spectroscopy and nuclear magnetic resonance spectroscopy(NMR)Was used to characteriz ．e its structure．Polarization curve，AC impedance spectroscopy(EIS)and static corrosion weight loss test were used to evaluate the corrosion inhib ．ition ofA T in l mol／L HCl solution，scanning electron microscope(SEM) analysis of its surface．Studies had shown that AT inhibitor on metal had good corrosion performance，when the A T content was 1 00 mg／L its inhib ．ition efficiency Was up to 99％．Langmuir adsorption isotherm model and EDS were used to study the mechanism of metal corrosion；the results showed that A T could form a film on carbon steel surface，thus effectively blocked the steel surface in contact with the hydrochloric acid solution，SO that metal could be protected． 2、Epoxy Phosphate(HEP)Was prepared with E44 and phosphoric acid (the ratio of epoxy group and hydroxyl group molar is 3．0：2．5)and FTIR was used to characterize its structure and proved the reaction between HI 万方数据 E44 E44 and phosphoric acid．Then we added HEP as a corrosion inhibitor to waterborne epoxy resin to make the paint with rust．The corrosion inhib- ition performance was investigated by polarization curves and electro— chemical impendence spectroscopy(EI S)．The results showed that it can improve the corrosion resistance with HEP．The tafel curves showed that the Rp of the electrode with HEP is much higher than the blank one indi —eating that the electrode with HEP had a lower corrosion rate than the blank one，which Was consistent with the EIS results． 3、We prepared waterborne epoxy coatings using AT as a corrosion inhi —bitor by addi