磷酸盐透波材料中石英纤维表面的防腐研究-分析化学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 西南科技大学硕士研究生毕业论文 西南科技大学硕士研究生毕业论文 第1页 摘 要 通过溶胶凝胶法，制备氧化铝、氧化硅、氧化铬及氧化锆溶胶，通过正 交实验和单因素分析得到制备氧化铝、氧化硅溶胶的最佳条件。将最佳的氧 化铝、氧化硅、氧化铬及氧化锆溶胶进行混合制各成复合溶胶，通过力学性 能分析得到最佳配比的复合溶胶。 分别将氧化铝溶胶、氧化硅溶胶、复合溶胶涂覆在石英纤维表面，经过 低温、高温处理得到涂层，通过TG—DTA—DSC、FT-IR、XRD分析手段，分析 了涂层不同温度下的结构变化。用表面张力测量系统分析了石英纤维分别与 氧化铝溶胶、氧化硅溶胶、复合溶胶的相容性，以及Al。0。涂层、SiO：涂层、 复合涂层与磷酸铬铝基体的相容性。结合A1。O。涂层、SiO：涂层、复合涂层 的耐酸性、抗拉伸强度和抗氧化性能的测试，探讨了涂层不同温度相变对涂 层性能的影响。 将三种涂层分别应用于石英纤维增强磷酸铬铝基复合材料中，研究了三 种涂层对复合材料其他的性能影响。结果表明：氧化铝涂层、氧化硅涂层、 复合涂层能大大改善石英纤维的耐酸性、抗氧化性、耐高温性能；能提高石 英纤维的增强效果；三种涂层使复合材料的介电常数和介质损耗有较小提 高。 关键词：溶胶凝胶法石英纤维氧化铝涂层氧化硅涂层复合涂层磷 酸铬铝 Abst Abst ract Aluminum oxide sol，silicon oxide sol，chrome oxide SOl and zirconia oxide sol were prepared by sol—gel method．The best preparation conditions of aluminum oxide sol and silicon oxide sol were determined by the orthogonal experiment and the single factor analysis．Aluminum oxide sol，silicon oxide sol， chrome oxide sol and zirconia oxide SOl were mixed on the different ratio．The best mix ratios of the composite sol were determined by the analysis of the quartz fiber’S mechanical properties． Aluminum oxide sol，silicon oxide S01 and composite SOl were coated respectively on the quartz fiber．The coatings were prepared by low temperature and high temperature treatment．The structure laws of A1203 coating，Si02 coating and composite coating in the heat process were researched by TG—DTA—DSC、FT-IR、XRD．The compatibility of the quartz fiber respectively with the aluminum oxide sol，silicon oxide sol and composite sol was researched by the surface tension measurement system，the same to the compatibility of the phosphoric acid chromium aluminum matrix respectively with the aluminum oxide coating，silicon oxide coating and composite coating．The acid resistance， tensile strength and oxidation resistance of the quartz fibers coated respectively aluminum oxide coating，silicon oxide coating and composite coating were tested．The coatings’performances were influenced by the phase changes on the different temperature．