葵花盘及柚子皮基多孔碳制备及在超级电容器中的应用-环境科学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 Abstract Abstract ‘’言宣萱皇ii宣iiiiiiiiiiiiiiiii宣iiiiiiiiiiiiiiii宣iii宣宣宣iii宣宣■皇宣宣iiiii宣iiiiiiiii the template agent S were washed by hydrofluoric acid(HF)．Analyzing with characterization test and electrochemical measurement，porous carbon materials derived from pomelo peels with mass ratio of CTAB and TEOS is 2／5 show better electrochemical performance．The nternal resistance was low and the capacitance was high，about 295 F og～．While the electrochemical performance of porous carbon materials derived from sunflower heads was bit poor，which lays a foundation for selecting carbon precursor． Hierarchical pore carbons derived from pomelo peels were synthesized using magnesium acetate pyrolysis MgO as a temple and KOH as activator．The influence of activator proportion and calcination temperature on the electrochemical performance was investigated by some electrochemical techniques．The relationship between pore structure and capacitance was analyzed by N2 adsorption and desorption， transmission electron microscope，scanning electron microscopy，Raman spectrum and X ray diffraction．Among these materials，optimal carbon material appeared the highest capacitance，which was 353 F·g。1(1 A·g。1)． Keywords：Supercapacitor； Biomass—based；Porous carbon； Activation method；Template method 万方数据 目 目 录 中文摘要 I ABSTR^CT ．II 第1章绪论 ．1 1．1引言 ．．1 1．2电化学超级电容器简介 ．．1 1．2．1超级电容器的工作原理及分类 l 1．2．2超级电容器的结构 2 1．2．3超级电容器的特点 3 1．2．4国P彤l-发展现状及前景 4 1．3超级电容器的碳基电极材料 ．．5 1．3．1碳材料电容性能的影响因素 5 1．3．2碳材料的类型 6 1．4生物质碳电极材料研究进展 ．．7 1．4．1生物质的定义 7 1．4．2柚子皮及葵花果盘的综合利用现状 8 1．4．3生物质碳电极材料的国P彤t-研究进展 8 1．5论文选题意义和研究内容 ．．9 1．5．1研究意义 9 1．5．2研究内容 9 第2章实验原料和方法 11 2．1实验原料及设备 ll 2．1．1实验原料 ．．1l 2．1．2实验设备 ．．1 l 2．2材料的表征 12 2．2．1扫描电子显微镜(SEM) ．1 2 2．2．2透射电子显微镜(TEM) ．12 万方数据 目录2 目录 2．2．3 X射线衍射(XRD) ．13 2．2。4氮气吸附脱附实验 一13 2．2．5 X射线光电子能谱(XPS) 一1 3 2．2．6拉曼光谱(Raman Spectra) ．1 3 2．3电化学测试 14 2．3．1循环伏安法(CV) ．．14 2．3．2恒电流充放电法(GCD) 14 2．3．3电化学阻抗(EIS) ．．14 第3章葵花盘基活性碳电极的制备及其电化学性能研究 15 3．1引言 l 5 3．2实验部分 15 3．2．1葵花盘基活性炭的制备 ．．15 3．3．2葵花盘基活性炭的