聚合物光波导薄膜的制备及改性研究-材料学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 摘 摘 要 本论文简述了平面光波导理论及光波导材料的发展现状，针对采用聚甲基丙 烯酸甲酯(PMMA)作为波导结构的芯层材料，聚二甲基硅氧烷(PDMS)作为包层材料 的可行性进行了分析，并比较了PMMA聚合物材料的多种改性手段和制备工艺。 论文工作主要利用无机纳米颗粒二氧化硅SiO：及有机染料分散红DRl来改性 PMMA，并对其改性工艺以及旋涂法和浸涂法的制膜工艺进行了探讨，关注改性 PMMA聚合物光波导薄膜的理化性质及光学性质。采用纳米SiO。颗粒掺杂PMMA， 旨在提高PMMA薄膜材料的热稳定性。由散射理论模型计算分析结果可知，通过控 制纳米颗粒的尺寸，便可减少其在紫外光部分的散射，为改性PMMA光波导薄膜 的紫外光刻成型提供便利。另一方面，采用DRl生色团分子掺杂PMMA，旨在使薄 膜样品极化后生色团沿一定方向取向，从而具有宏观二阶非线性效应，但保持时 间较短。而利用表面改性的纳米$i0：颗粒与PMMA的氢键作用，可以抑制生色团 的重新取向，延长非线性效应的弛豫时间。多种先进的测试手段和表征分析的结 果表明：纳米级SiO：可以较大地提高PMMA芯层的热稳定性，使无规PMMA的玻璃 化转变温度从70C提高到110C，使其在较高的温度下正常工作；同时纳米级 SiO：和DRl的掺入未显著影响PM薄膜在紫外到可见波段的透过率。生色团分 子DRl的加入，可以使PMMA芯层材料具有二阶非线性效应，纳米级表面改性的 SiO：，使薄膜材料的电光系数增大，电光系数d33由5．02．10呻增加到12．66．10呻， 且弛豫时间延长。 本文所研制的改性PMMA聚合物薄膜成本低且性能优良，研究工作对于聚合 物光波导器件的研制和集成光路的发展具有一定的理论参考价值和实践指导意 义。 关键词：光波导薄膜； 聚甲基丙烯酸甲酯；光学性能 AbstractIn Abstract In this paper,the theory of planar optical waveguide and development of optical waveguide material were firstly reviewed，and the feasibility of using PMMA as the core layer and PDMS as the substrate and superstrate were analyzed．Several methods of modification and preparation were compared in this paper．The modification process of PMMA with llano·silicon dioxide and dye，various physical chemistry and optical performance of polymer waveguide thin films were investigated，to improve the termal stability of materials by taking nano—silicon dioxide particales into PMMA． The ultraviolet call be utilized not onl y decreasing aging but also for photo—induced bleaching by control the llanO-particle size．On the other hand，The samples added dipersion red 1 had nonlinear optical effect after poling because of the tropism of dye． Howerver,it can not be kept in a long time．Hydrogenous bond between nano-silicon dioxide and PMMA would restained the tropism of dye，enhancing the second order nonlinear optical effect of the film and keeping long．By using of various advanced measurement technologies it is showed that nano—silicon dioxide improve PMMAs thermal stability,the polymer thin films ar