石墨烯二氧化硅三维杂化材料制备和其在改性酚醛泡沫中.PDF

石墨烯/ 二氧化硅三维杂化材料的制备及 其在改性酚醛泡沫中的应用 罗摇 霞摇 摇 俞科静摇 摇 钱摇 坤 (江南大学生态纺织教育部重点实验室,无锡摇 214122) 文摇 摘摇 为了得到结构和力学性能良好的酚醛泡沫,利用原位生成的方法制备了石墨烯/ 二氧化硅 (GNPs/ SiO )杂化材料,并将其用于酚醛泡沫的制备当中。 对杂化材料进行了红外光谱分析,透射电镜以及X 2 射线衍射分析,验证了石墨烯表面SiO 球体(粒径在150 ~180 nm)的存在。 对泡沫的结构和压缩性能进行对 2 比分析,发现三维杂化材料相比二维石墨烯能够更好的改善酚醛泡沫的泡孔结构,杂化材料为0.5wt%时, GNPs/ SiO 改性酚醛泡沫的泡孔尺寸更小,结构更均匀;同时杂化材料改性酚醛泡沫表现出更优异的力学性 2 能,其压缩强度和弹性模量分别达到0.22和4.1MPa,比纯酚醛泡沫分别提高了91%和86%。 关键词摇 杂化材料,酚醛泡沫,泡孔结构,力学性能 中图分类号:TQ328.2 DOI:10.12044/ j.issn.1007-2330.2017.05.003 Fabrication of GNPs/ SiO Hybrids Materals and Their Application in2 Phenolic Foams Modification LUO Xia摇 摇 YU Kejing摇 摇 QIAN Kun (Key Laboratory of Eco-Textiles,Ministry of Education,Jiangnan University,Wuxi摇 214122) Abstract摇 In order to prepared the phenolic foams with excellent cell structure and mechanical properties,the graphene/ silica (GNPs/ SiO ) hybrid materialswere prepared by the method of in situ formation. The graphene and 2 GNPs/ SiO hybridmaterialswereusedinthepreparationofphenolicfoams. Thecellsstructureandcompressionprop鄄 2 ertiesofthephenolicfoamswereanalyzed,andfoundthathybridmaterialscanimprovedthebubblesstructureandme鄄 chanical propertiesmoreeffectively. andtheInfraredSpectroscopy(FT-IR),transmissionelectronmicroscopy (SEM) and X-ray diffraction (XRD)analysiswere conducted and confirmedthe silica sphereswereformed onthe surface of the GNPs. Thesilicashowsaparticlesizeof 150-180nm. Thephenolicfoamsshowedmoreuniformcellstructureand small cell size whenthecontentof hybridmaterialswas0.5wt%. GNPs/ SiO modifiedphenolicfoamsshowedtheex鄄