镍复合电镀新工艺及其阴极过程研究-化学工程专业论文.docxVIP

优秀毕业论文 精品参考文献资料 广东工业大学硕士学位论文及 广东工业大学硕士学位论文 及EDS分析可知复合镀层和光亮镍层表面平整、光亮，结构细致、均匀，且复合镀层 中均匀分散着大量的微粒，光亮镍层有少量微孔。不同腐蚀介质中所得Tafel曲线和电 化学阻抗谱表明复合镀层在酸性和中性介质中耐蚀性优于光亮镍层，而在碱性介质中 复合镀层的耐蚀性比光亮镍略差；多层镍／微孔铬在中性、酸性、碱性介质中都较易发 生腐蚀，但因其铬镀层表面存在大量微孔，．分散了腐蚀电流，降低了腐蚀速度，从而 使多层镍／微孔铬在三种腐蚀介质中的耐蚀性均好于多层镍／铬。 5、采用电化学工作站研究镍电沉积的阴极过程发现：阴极极化曲线表明光剂能增 大镍电沉积的阴极极化，使镀层表面平整、光亮；复合镀微粒SN．B和分散剂SN．A对 镍电沉积阴极极化几乎无影响。电化学阻抗谱表明光剂能增大电化学阻抗，阻碍镍离 子还原，使镀层变得光亮；SN—B和SN．A对镍电沉积的电化学反应电阻影响较小，但 SN-B能增加溶液电阻。阴极极化曲线和电化学阻抗谱分析结果一致。 6、在前面研究市售纳米微粒作镍封微粒的基础上，探索了一种更简单、经济的镍 封新工艺，即向光亮镍镀液中直接滴加Ba配合物制备含BaS04微粒的复合镀镍(镍封) 液，电镀后可使铬镀层微孔密度达6x 104个／cm2以上。通过单因素实验得出制备镍封镀 液的较优工艺条件为：滴加量10 mL／L、滴加速率30 s／mL、搅拌强度4级、温度40℃； 通过CASS盐雾试验表明该工艺的多层镍／微孔铬具有较好的耐蚀性。虽然此新工艺具 有简单、成本低、耐蚀性好等优点，但镀液静置3 d后，铬镀层微孔密度低于1×104个 ／cm2，微粒在镀液中稳定性较差，很难用于实际生产。 关键字：镍封；复合镀；镍封微粒；分散剂；微孔密度；耐蚀性 II 万方数据 AbtractAbtract Abtract Abtract Corrosion is of the main forms which disable the function of meterials．Meterial Corrosion caused great harm，namely it bring economic losses and many serious accidents， consume large amount of valuable and energy and pollute environment．The process of Composite electrodeposition is one of surface protection technology and only need simple equipment that is operated easily,low temperature．Which Composite coatings not only improve corrosion resistance，wear resistance，oxidation resistance at high temperature and other properties of metal surface，but also materials，energy and manufacturing cost，it is widely used in the machinery,electronics，and other fields．The goal of this article is to obtain the nickel sealing process of good corrosion resistance of coatings and high stability of nickel sealing bath．The specific research contents and conclusions follows： 1．Select the appropriate nickel sealing particles．Composite phting((also called nickel sealing)that were done in bright nickel plating bath that that were added nano—A1203 powder，nano-A1203 emulsion，nano-Ti02 powder and SN·B respectively be prepared bright nickel-based composite coating，leading to multilayer nickel／chromium co