喷雾干燥辅助表面活性剂自组装制备新型SiO2介孔材料Preparation.PDF

2006 年第64 卷 化 学 学 报 Vol. 64, 2006 第9 期, 894～898 ACTA CHIMICA SINICA No. 9, 894～898 ·研究论文· 喷雾干燥辅助表面活性剂自组装制备新型 SiO 介孔材料 2 张蝶青 万 颖 李和兴* (上海师范大学化学系 上海 200234) 摘要 将喷雾干燥辅助表面活性剂自组装应用于介孔 SiO2 材料的合成, 先后制备了2 种无机 SiO2 介孔材料(PW-P 和 PW-C)和2 种苯基修饰的有机-无机SiO2 介孔材料(Ph-PW-C 和Ph-PW-C-S), 结合XRD, BET, SEM 和TEM 等表征, 初 步讨论了喷雾干燥过程中表面活性剂种类、硅源以及反应介质的酸碱性对所制备材料的表面组成和形貌、比表面积、 孔容以及孔道结构等的影响. 关键词 喷雾干燥辅助自组装; SiO2 介孔材料; 苯基修饰 Preparation of New Mesoporous SiO by Aerosol-drying Assisted 2 Surfactant Self-assembly ZHANG, Die-Qing WAN, Ying LI, He-Xing* (Department of Chemistry , Shanghai Normal University, Shanghai 200234) Abstract Two kinds of mesoporous inorganic SiO (PW-P and PW-C) and two kinds of mesoporous phe- 2 nyl-modified SiO2 (Ph-PW-C and Ph-PW-C-S) were prepared by aerosol-assisted self-assembly. Based on XRD, SEM, TEM and BET characterizations, the effects of the preparation conditions on the surface com- positions, the surface morphology, the surface area, the pore volume, and the pore structure of the prepared samples were examined by changing the surfactant types, the silicate sources and the acidic/basic media used during the aerosol-assisted self-assembly. Keywords aerosol-assisted self-assembly; mesoporous SiO2 ; phenyl modification [1] 介孔材料