歧化松香皂脱色精制工艺研究及脱色机理探讨.PDFVIP

4 0 2 V o.l 4 0 N o. 2 2006 3 B iom ass Chem ical Eng in eer ing M a r. 2006 朱岳麟 汤丽妮 胡学寅 郭 红 焦健 ( 北京航空航天大学 材料科学与工程学院 北京 100083) : 针对目前国 市场上歧化松香皂产品颜色过深的问题 深入研究了歧化松香皂脱色的实验方法 确定了 SQ Z- 9 脱色方法是一种工艺简单成本低廉且能显著降低现有歧化松香皂产品颜色的脱色方法 可将特级歧化松香皂的加纳色 号从 8 降至 3根据实验研究结果 在广西梧州松脂股份有限公司进行了歧化松香皂脱色工业中试针对中试中发现的 局部过热和脱色产物透明度下降问题 改进了歧化松香皂脱色工艺 并采用红外紫外分析手段对其脱色机理进行了分 析 : 歧化松香皂; 脱色机理; 中试 : TQ351. 47 : A : 1673- 5854 ( 200 6) 02 - 00 15 - 04 R efin ing T echnics of D isproportionated Rosin Soap and Its D ecoloring M echanism A nalysis ZHU Y u e- lin TANG L i-n i HU X u e-y in GUO H ong JIAO J ian ( D ep artm ent o f M ater ia l S ience and Eng ineer ing Be ij ing U n ive rsity of A eronautics and A stronautics Be ij ing 100083 Ch ina) A bstrac t: A mi ed at the co lo r prob lem o f d isproportionated ro sin soap in present dom estic m arket ros in soap deco loration exp er-i m ent s are thorough ly stu died in th is p aper. T he deco lo ration by SQZ-9 is asce rtained as a smi p le econom ica l prom inent process w hich can reduce the co lo r o f dispropo rtiona ted ros in soap from G ardne r co lor num ber 8 to 3. Based on the results in G u angx iW uzhou R osin L td. Co. a p ilo t exp ermi entw as done dur ing w h ich tw o prob lem s appeared to be the p artia lly h igh tem- p erature o f soap and descend ing o f the transp arency of the deco lored d ispropo rtionated ros in. A s the solution to the problem s the deco lor ing technics w as mi proved. The deco ring m ech an ism is a lso supposed in th is pap er. K ey w ord s: d isproportionated ro sin soap; p ilo t exp er mi ent; deco lor ing m echanism A BS