试验原料及方法.doc

doi： doi：10.3969/j.issn.1007-7545.2018.10.011 吴星琳1，衷水平2，罗仁昆1，陈杭2，张焕然1，王俊娥2，林泓富3，吴健辉3 (1.紫金铜业有限公司，福建 龙岩，364204； 2.厦门紫金矿冶设计有限公司，福建 厦门，361115； 3.紫金矿业集团股份有限公司，福建 龙岩，364200) 摘要：采用氯酸钠＋硫酸浸铜、氢氧化钠浸碲、中和沉碲的方法从碲化亚铜渣中制取二氧化碲。在氯酸钠︰碲化亚铜渣=0.5、硫酸70 g/L、反应温度80 ℃、液固比5︰1、反应时间2 h的条件下，铜和碲的浸出率分别为99.33%、10.58%。酸浸渣在反应温度90 ℃、NaOH 100 g/L、液固比5︰1、反应时间2 h的条件下进行碱性浸出，碲浸出率为99.13%。利用浓硫酸调节碱浸液pH至5.5，碲沉淀率为100%，沉淀产物为TeO2，碲含量为75.76%。 关键词：碲化亚铜渣；氯酸钠；二氧化碲 中图分类号：TF843 文献标志码：A 文章编号：1007-7545（2018）10-0000-00 Extraction and Preparation of Tellurium Dioxide from Copper Telluride Slag WU Xing-lin1, ZHONG Shui-ping2, LUO Ren-kun1, CHEN Hang2, ZHANG Huan-ran1, WANG Jun-e2, LIN Hong-fu3, WU Jian-hui3 (1. Zijin Copper Industry Co., Ltd, Longyan 364204, Fujian, China; 2. Xiamen Zijin Mining and Technology Co., Ltd, Xiamen 361115, Fujian, China; 3. Zijin Mining Group Co., Ltd, Longyan 364200, Fujian, China) Abstract：TeO2 was prepared from copper telluride slag by copper leaching with sodium chlorate and sulfuric acid, tellurium leaching with sodium hydroxide, and tellurium precipitation with neutralization. The results shows that leaching rates of copper and tellurium is 99.33% and 10.58% respectively under the conditions including dosage of sodium chlorate of 0.5 time of copper telluride slag, sulfuric acid concentration of 70 g/L, reaction temperature of 80 ℃, L/S of 5, and reaction time of 2 h. Leaching rate of tellurium with alkaline is 99.13% under the conditions including temperature of 90 ℃, L/S of 5, and reaction time of 2 h. Tellurium neutralization precipitation rate is 100% at pH value of 5.5 adjusted by vitriol. Precipitation product is tellurium dioxide with tellurium content of 75.76%. Key words：copper telluride slag; sodium chlorate; tellurium dioxide 碲广泛应用于冶金[1-2]、能源[3]、化工[4]、电子电气[5-6]等行业。碲是一种稀散元素，除少量以单质存在外，大部分与铅、铋、铜、铁、锌、镍、金、银以及铂族等元素形成碲化物、碲硒（硫）化物、碲的氧化物和含氧酸盐等[7-8]。由于碲矿物的分散性及稀缺性，80%的碲是从铜阳极泥中提取的[9-10]。铜阳极泥经预处理[11-13]得到含碲溶液，利用铜粉置换得到碲化亚铜渣。碲化亚铜渣作为危险固废大多数企业选择直接外售，虽可节约一定的无害化处置费用，但铜、碲、金、银等有价金属计价系数低，影响企业经济效益。基