690合金在25℃的5MNaCl溶液中之电化学极化与应力腐蚀行为研究.PDF

523540200512 Journal of Chinese Corrosion Engineering, Vol.19 No.4, PP. 523~540 (2005) 690 255M NaCl 1 2 1 * Study on the Electrochemical Polarization and Stress Corrosion Cracking Behaviors of Alloy 690 in 5M Chloride Solutions at 25 1 2 1 Y. Y. Chen* , L. B. Chou , H. C. Shih o 690 25 C 5 M pH pH 4 pH (0.3 - 8.52) pH ( 3) pH 3 pH 690 1 Department of Materials Science and Engineering, National Tsing Hua University. 2 Materials Research Laboratories, Industrial Technology Research Institute. franklin_chen_1@ -523- 2005 12 ABSTRACT o An experimental, potential-pH diagram was constructed for the nickel-based Alloy 690 in 25 C concentrated (5M) sodium chloride solution, using an cyclic polarization method. The domains of immunity, general corrosion, passivation, and pitting in 5M NaCl solutions were defined. At pH 4 the passive region subdivided into areas of perfect passivation, imperfect passivation, and pitting. After anodic polarization, the surface of each specimen was carefully examined metallographically. Pitting corrosion was observed over the entire