利用压力影响恒沸点由反应精馏精制THF-Core.PDF

第 18 卷 　第 2 期 计算机与应用化学 Vol18 , No2 2001 年 3 月 28 日 Computers and Applied Chemistry March , 2001 利用压力影响恒沸点由反应精馏精制 THF 刘庆林 肖剑 　 厦门大学化学工程系 , 厦门 　361005) (南京大学化学工程系 , 南京 　210093) 摘要 : 研究压力如何影响恒沸点 , 探索改变操作压力由反应精馏精制四氢呋喃 ( THF) 可行性。模拟计算考察了 压力对 THF/ 水体系恒沸点的影响 , 结果表明体系压力增加 , 恒沸物中 THF 摩尔分率减少。通过两塔在不同压力 下操作 , 利用反应精馏技术可从 1 ,4丁二醇制备高纯度的 THF 。 关键词 : 精馏 ; 反应精馏 ; 恒沸物 ; 四氢呋喃 中图法分类号: TQ 0288 文献标识码 : A 文章编号 : (2001) Synthesis of Tetrahydrofuran from Butanediol by PressureSensitive Reactive Distillation 1 2 LIU Qinglin 　　XIAO Jian 1 ( Department of Chemical Engineering , Xiamen University , Xiamen 　361005) 2 ( Department of Chemical Engineering , Nanjing University , Nanjing 　210093) Abstract : The objective of this paper was to investigate the relation of azeotrope to the system pressure , and further to study the possibility for the synthesis of tetrahydrofuran ( THF) from butanediol by pressuresensitive reactive distillation. The effect of pres sure on azeotropic composition for the system of THF / water was studied by numerical simulation , and it was found that the mole fraction of THF in the azeotrope was reduced with the increase of pressure. While it is difficult to predict whether the azeotropic composition is increased with pressure by o