离子交换树脂在地质样品犁狉荦犱同位素测定中的应用.docVIP

离子交换树脂在地质样品Sr-Nd同位素测定中的应用 刘文刚注：本文 注：本文为国家重点基础研究发展计划“973”项目（编号 2015CB453000）、中国地质调查局地质调查项目（编号 12120115013501）联合资助成果。 作者简介：刘文刚，男，1988生。助理工程师，主要从事Rb-Sr和Sm-Nd同位素测试。Email：liuwg1988 @163.com。 中国地质调查局天津地质矿产研究所，天津，300170； The Application of Ion Exchange Resins in Geological Samples for Sr-Nd Isotopic Assay LIU Wengang, LIU Hui, LI Guozhan, ZHOU Hongying, XIAO Zhibin, TU Jiarun, LI Huimin Tianjin Institute of Geology and Mineral Resource，China Geological Survey，Tianjin，300170，China 内容提要：Rb-Sr和Sm-Nd同位素测年及同位素示踪方法在同位素地质年代学和同位素地球化学中有非常广泛的应用。目前，Rb-Sr和Sm-Nd同位素质谱测试方法通常需要对Rb-Sr和Sm-Nd进行分离纯化，因此，如何对地质样品中的Rb、Sr、Sm和Nd进行分离富集对测试结果准确与否起到至关重要的作用。离子交换分离法是Sr-Nd同位素化学前处理阶段应用最广泛的分离方法，本文结合笔者近几年的研究工作，系统介绍离子交换树脂在Sr-Nd同位素测试中应用的发展过程和现状，重点介绍几类使用率较高的离子交换树脂（Dowex50W树脂、AG50W树脂、锶特效树脂、LN树脂、P507树脂等）的优缺点，以及各自的萃取反应机理，探索和讨论未来离子交换树脂在Sr-Nd同位素测试中应用的发展趋势。 关键词：地质样品；Rb-Sr, Sm-Nd； 分离；离子交换树脂 Abstract Rb-Sr and Sm-Nd isotopic dating and isotopic tracer method are widely applied in both isotopic geochronology and isotope geochemistry. At present, it is necessary to isolate and purificate Rb-Sr and Sm-Nd for the analysis of Rb-Sr and Sm-Nd by isotope mass spectrometry. Therefore how to isolate and enrich Rb, Sr, Sm and Nd in geological samples plays an important role in improving the accuracy of the analysis results. HYPERLINK javascript:showjdsw(showjd_0,j_0) Ion exchange separation method is most widely used in the pre-processing stages of isotope chemistry. Combining with the authors research work in recent years, the development and status of HYPERLINK javascript:showjdsw(showjd_0,j_0) ion exchange separation method applied in isotope analysis was introduced systematically in this paper. In particular, we focus on describing not only the strengths and weaknesses of some kinds of ion exchange resins(Dowex50W resin; AG50W resin; Strontium spec resin; Ln Spec resin; P507 resin) which were used frequently, but also the respective extraction mechanisms.At last, the development trend of ion exchange resin applied in Sr-N