zno纳米线的制备及在敏化太阳能电池中的应用材料物理与化学专业论文.docxVIP

4．5mmol／L，水浴温度为95。C，生长时间为9h时，可以获得长径比达20．56 4．5mmol／L，水浴温度为95。C，生长时间为9h时，可以获得长径比达20．56 的ZnO纳米线。 2．采用连续离子层吸附反应(SILAR)法在ZnO纳米线上沉积CdS量 子点，并将其组装成敏化太阳能电池。探讨SILAR过程中CdS的循环次数 以及不同长径比ZnO纳米线对太阳能电池性能的影响。研究发现：随着CdS 的SILAR循环次数从2次增至16次，太阳能电池的效率先增加后减小；随 着ZnO纳米线长径比的增大，ZnO纳米线上吸附的CdS量子点数量增多， 吸收光谱范围得到加宽，太阳能电池的转换效率得到提高。在CdS循环次 数为12次，ZnO纳米线的长径比为20．56时，CdS量子点敏化ZnO纳米线 太阳能电池可以达到最高的光电转换效率0．401％。 3．采用玫瑰红B直接吸附(DA)法敏化ZnO纳米线并组装成敏化太阳能 电池，研究了玫瑰红B的浓度和ZnO纳米线长径比对染料敏化太阳电池光 电性能的影响。研究结果表明：当玫瑰红B浓度为0．2mmol／L时，ZnO纳 米线的长径比为20．56时，太阳能电池可达到最佳性能，此时的短路电流密 度为3．043mA／cm2，开路电压为0．406V，填充因子为0．341，光电转换效率 0．421％。 4．为了加宽太阳光谱的吸收范围以及弥补单一敏化剂所产生的缺陷， 制备CdS和玫瑰红B共敏化ZnO纳米线太阳能电池。研究发现，采用CdS／ 玫瑰红B共敏化ZnO纳米线可以提高太阳能电池的短路电流密度和光电转 换效率，与CdS和玫瑰红B单一敏化ZnO纳米线太阳能电池对比，转换效 率分别提高了28％和22％。 关键词：染料敏化ZnO纳米线CdS玫瑰红B光电性能 II 万方数据 PREPAR PREPAR ATIoN oF ZNo NANOWlRES AND ITS APPLIC觚’IoNS IN SENSITIZED SoLAR CELLS ABSTRACT As a clean and renewable energy,solar energy is helpful to achieve the sustainable development of human society,but the efficient utilization and proper storage of solar energy is an important issue to he addressed in the future．The dye-sensitized solar cells was considered as one of the most promising new type of solar cell for the next generation due to its simple manufacturing process，lower cost and environmental fiiendship．Generally,Ti02 nanoparticles were used for the photoanode of sensitized solar cells，but poor contact between Ti02 nanoparticles and the low electron mobility of Ti02 resulte in the lower conversion efficiency of sensitized solar cell．Because ZnO nanowires has higher electron mobility， direct transport passway for electron，a wealth of raw materials and simple preparation process，sensitized solar cells based on ZnO nanowires have better application prospect．In this paper,we fabricated high aspect radio of ZnO nanowires as photoanode by chemical bath deposition(CBD)method and used CdS quantum dots and organic dye rose Bengal sensitized ZnO nanowires to assemble sensitized solar cell．After that，the structure and