ti2aln三元陶瓷的制备及其腐蚀剥离行为研究材料科学与工程专业论文.docxVIP

度、球磨对腐蚀剥离过程的影响。结果表明：n2AlN在浓度为2％的HF溶 度、球磨对腐蚀剥离过程的影响。结果表明：n2AlN在浓度为2％的HF溶 液中，反应2h，有气泡产生，产物为厚度大约为2．5 nm的薄片，这说明 HF溶液的浓度过低或过高、反应时间过短或过长都不能或使得Ti2A1N腐 蚀剥离不彻底或者过腐蚀导致其产物进一步被氧化。采用球磨腐蚀剥离， 产物是片状的Ti2AIN。 以不同浓度的盐酸、硫酸、硝酸、氢氧化锂、氢氧化钠等溶液为腐蚀 介质，以合成的Ti2A1N为腐蚀剥离对象，在水热条件下进一步研究了其腐 蚀剥离行为。利用XRD及FESEM对不同工艺下腐蚀产物的相组成及微观 形貌进行了分析。结果表明：Ti2A1N抗酸的腐蚀能力弱于抗碱的腐蚀能力。 同时，在水热条件下Ti2A1N晶格中的Al层原子和Ti层原子均与酸／碱中的 I-Y／OH发生了反应，进而破坏了其层状晶格结构。在S042‘，C1。，N03离子 的作用下，最终生成了不同晶型的Ti02；在碱溶液中最终生成了钛酸盐纳 米纤维。 关键词：Ti2AIN，MAX相，陶瓷，热爆反应，腐蚀 Ⅱ 万方数据 SYNTHESIS SYNTHESIS AND CORROSION BEHAVIOR OF Ti2AIN TERNARY CERAMIC S ABSTRACT The M匕Ⅸphases are layered ternary compounds．A new family of two-dimensional materials calledⅣⅨene are produced by the etching out of the A layers from M_AX phases．MXenes are expected to be good candidates for a host of application in Supercapacitors，lithium-ion battery．Ti2A1N is one typical member of nitrides㈣phases，therefore，it iS necessary to develop rapid and low-cost ways to prepare high purity and small size Ti2A1N ceramic in mass scale，which iS the foundation of its corrosion．In this work．the new method for synthesizing Ti2A1N and its corrosion behavior in solution were investigated． The powder mixture of Ti，Al and TiN was used as the raw materials with a designed composition．The mixture was firstly cold．pressed into cylindrical discs and directly put into ail air fiLTlace which Was preheated to 650℃-850℃． After holding for 2-5 min，the reacted discs were taken out and cooled down quickly to ambient temperature．The structures and compositions of the as-prepared products were characterized byⅪ己D，FESEM and HRTEM．The effects of starting composition，TiN particle size，preheating temperature，the compacts’volume(height，diameter)and holding time of the prefabricated discs on compositions，microstructure of as-prepared Ti2A1N were investigated，and the formation mechanism for Ti2AIN Was also proposed．Results show that purity of Ti2AIN increase in direct ratio with Al content and later decrease with continuously incre