超长排列硅及硅氧纳米管的制备和光学性质研究物理学凝聚态物理专业论文.docxVIP

簟州大学博士学位论文发射峰，其中514 簟州大学博士学位论文 发射峰，其中514 nlTl的发光峰最强并伴有两个位于415 nm年11624 nlTl的肩峰。这个蓝绿 发射是由纳米管的缺陷引起的。 4．以悬空排列的PVP纳米线为模板在HWCVD系统中制备了超长排列的Si 纳米管(约4 mm)，并对纳米管的形貌，成分和光学性质进行了表征。分别利用烘 烤PVP纳米线和调节沉积时间来控制Si纳米管的内径和壁厚。由此，可以在不影 响排列长度和取向程度的情况下控制Si纳米管的直径。在反应室不同的位置得到包 裹程度不同的纳米管，这是腔体巾不同区域解离气体的浓度和运动状态不同引起 的。管壁由纳米颗粒或纳米柱组成，但内表面比外表面更加光滑平整。Si纳米管的 微区PL谱巾出现了红、绿、蓝三个发光带。这些发光带分别是由量了限制一发光 中心过程和缺陷巾心的辐射复合引起的。 关键词：电纺丝；取向排列；TUFT过程；SiOx纳米管；Si纳米管；光致发光 II 兰州大学博士学位论文Abstract 兰州大学博士学位论文 Abstract Si nanotubes and SiOx nanotubes are compatible with Si based microelectronic existing widely in information industry and have prospective applications in the optical materials，nanodevice，glass fber,catalysis and biological field，SO they are research hotspot and frontier field nowadays．Meanwhile，the assembly system of nanomaterials also became the research emphasis at present．It emphasized that people designed， assembled and created new system according to their own will，and made this new system have expectable characteristics．Therefore，ultra·long and aligned semiconductor nanofibers and nanotubes have obvious advantages in assembly and application of nanomaterials．The thesis mainly introduced the preparation of ultra—long aligned polymer nanofibers and doped semiconductor nanofibers by electrospinning，and the fabrication of aligned Si and SiOx nanotubes by TUFT process，as well as the investigation of PL mechanism of nanotubes． 1．Electrospinning with two parallel electrodes is used for fabricated aligned PVP nanofibers．The orientation degree and the length of aligned nanofibers are enhanced by improving the electrospinning technological process．The highly oriented nanofibers were 200 nnl in diameter and their length Was up to several millimeter．There are three basic requirements for obtaining highly aligned PVP nanofibers in this process：(i)using the suspended sheet metal as parallel electrode；(ii)choosing a suitable gap width and a suitable needle tip-to-target distance；(iii)the jet emerging from the Talylor’S co