高稳定性钯纳米复合材料的制备及性能研究精细化工专业论文.docxVIP

高稳定性钯纳米复合材料的制备及性能研究Preparation 高稳定性钯纳米复合材料的制备及性能研究 Preparation and Stabilization of Palladium Nanoparticles Ins ide Mesoporous Materials and Metal Oxide Abstract Metal nanoparticles，because of their excellent properties such as large specific surface area and high surface energy，were widely used in catalysis，biomedical，energy and many other fields．However，serious aggregation was usually happened when they used in practice，and resulted in the degradation of performance even inactivation．Therefore，how to design effect method to stabilize metal nanoparticles Was the key to ensure their best use． Mesoporous materials，as to their regular mesoporous structure and high specific surface area,were usually regarded as the carrier of metal nanoparticles．Through the restriction of channels，not only realized the stabilization of metal nanoparticles，but also contributed to the transportation of reactants．Metal oxides，which could interact with metal nanoparticles and improved their performance，were also used to support and disperse metal nanoparticles．Base on the stabilization ofmetal nanoparticles，three kinds ofmetal／supporter nanocomposites were synthesized by using mesoporous materials and metal oxide as the supporter respectively． (1)A simple and effective method was developed for the controlled anchoring of Pd nanopartides inside the channels of MCM一4 1．So that,Pd／MCM-4 1 with tiny metal size(-3 nm)，high stability and activity Was obtained．This material exhibited good catalytic activity in the couple reaction of iodobenzene and phenylboronic acid．After 5 minutes’reaction，the conversion of iodobenzene reached 9 1．42％and didn’t observe obvious decrease after recycling 4 times． (2)Carbon sphere with well mesoporous structure，high specific surface area and uniform pore size Was synthesized by using Si02 nanoparticles as the template．Pd nanoparticles could be well dispersed in the mesopores of this carbon spheres and got Pd／meso-Carbon．This materials showed excellent catalytic a