金属粉末球磨生成相研究材料加工工程专业论文.docxVIP

优秀毕业论文 精品参考文献资料 Ab Ab stract The reaction milling which is based on the principles of mechanochemistry theory takes more and more important part in deVeloping new materials．The present researches have been foucs on the reactions in solid—solid and solid—gas systems，but few in the solid．1iquid systems．In solid-liquid system，metal is milled in organic solvent，studies on metal milled in inorganic s01Vent are eVen fewer． Taking conlparison with mechanical alloying，this paper inVestigates the rule of reactions of titanium，titanium dioxide，ferrum and ferric oxide milled in neutral water．The experimentalis as follow： 1．In the Ti．H20 system，titanium is milled in distilled water，with the ratio of balls and raw material of 60：l，rotate speed of the mill of 370rpm．After 90h milling， solid solution of ferrum and titanium has been found．The surplus ferrum may be that stripped off from the milling baUs．Lattice parameter of ferrum increased by 1．1 2％with the products being reflned to 80-l 00nm．Under the same conditions above but changing pH value of water with hydrochloric acid of sodium hydroxide to 3 and 1 1 respectively，it is showed that the pH Value doesn’t innuence the formation of products but the speed of the reactions!Speed of reaction is highest in neutral solution，followed by acid and that of alkaline is the slowest． 2． As to titanium oxide．fcrrite oxide and titanium-ferrum system，raw material ls milIed in distilled water，with the ratio of balls and raw material，rotate speed of the mill of 3 00rpm．The result shows that the titanium oxide has entered into the lattice of ferrite oxide，with the existence of little titanium oxide and ferrite oxide， while in ferrum，titanium oxide system，it is indicated that the two are hard to react with each other，with the appearance of a little FeTi03．Products in the svstems above are all uniform in distfibution and nanometer in scale，to the leVel of 20．100 nm． 3． Mechanical aUoying technology is adopted in Q—Fe203一Ti02，Fe-Ti，Fe。Ti02 syste