固态原位电还原TiO2制取Ti的阳极和电极过程-Journalof.PDF

第33 卷第9期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol33, No. 9 2 0 12 年 9 月 Journal of Northeastern U niversity( Natural S ien e) Sep. 2 0 1 2 TiO Ti 2 关长龙, 张廷安, 豆志河 ( , 110819) : T iO T i , 2 , T iO T i , , , 2 CO , : C+ 2O2- - 4e= CO T iO T i 2 2 2 : 2T iO + C= 2T iO+ CO , 2T iO+ C= 2T i+ CO , 2CaO+ C= 2Ca+ CO Ca T iO 2 2 2 2 2 , T iO T i T iO Ca T iO 2 2 2 : ; ; ; ; : T F 823; T F 80 1. 1 : A : 1005-3026( 2012) 09- 1307-04 Investigation of Anode and Electrode Processes of Solid State in Situ Electrochemical Reduction from TiO to Ti 2 G UA N Chang-long , ZH A N G Ting-an, D O U Zhi-he ( S hool of Materials Metallurgy, Northeastern University, Shenyang 110819, China. Corresponding author: GUA N Chang-long, E-mail: g long 1001 @ 163. om) Abstract: The anode pro ess of solid state in situ ele tro hemi al redu tion from TiO to Ti was 2 studied by y li voltammetry and the w hole ele trode pro ess w as analyzed. T he results show that the anode pro ess is a one-step reversible oxidizing rea tion of two- harge w ith the produ ts undissolved and CO is produ ed at arbon anode. The anode rea tions an be expressed as C+ 2 2- 2O - 4e= CO . The general ele trode rea