玻璃纤维织物增强聚丙烯复合材料浸渍机理及界面结合性能研究机械工程专业论文.docxVIP

北京化工大学硕士学位论文FRTC工业大规模低成本制造提供一定的理论参考。 北京化工大学硕士学位论文 FRTC工业大规模低成本制造提供一定的理论参考。 在传统界面改性的基础上，本文借助纳米颗粒的协同增强增韧的特性， 通过两步法制备工艺，将纳米二氧化硅(Si02)采用KH550硅烷偶联剂 以化学接枝的方式修饰到玻璃纤维表面，并与PP树脂复合制备复合材料， 采用界面剪切强度(IFSS)、界面断裂韧性(GIIc)、动态机械性能(DMA)、 拉伸和弯曲强度来综合表征复合材料力学性能，为玻璃纤维增强聚烯烃类 复合材料界面设计提供一定的参考。 关键词：玻璃纤维织物，聚丙烯，浸渍机理，纳米SiO：，界面修饰 万方数据 ABSTRACTRESEARCH ABSTRACT RESEARCH ON THE IMPREGNATIoN MECHANISM oF GLASS FABIRC／PoLYPRoPYLENE CoMPoSITES AND INTERFACE BoNDlNG PERFoRMANCE ABSTRACT With the excellent design ability,high specific strength and stiffness，high damage tolerance，long prepreg storage cycle，short molding cycle，recyclability, low manufacturing and maintenance cost，fiber reinforced thermoplastic composites(FRTC)are popular with academia and industry．Thermoplastic polymer is pseudoplastic fluid，which displays shear thinning behavior when flowing through the fiber porous media．One of the key factors to prepare manufacture FRTC is how to characterize the non—Newtonian viscosity behavior of thermoplastic melt accurately．The interface of composites is a bridge which transmits stress from polymer matrix to fiber．The performance of glass fiber reinforced Polypropylene(PP)is dependent to a great extent on the properties of glass fiber／PP composites．The synergistic reinforcing and toughening of composites is hard tO realize in the traditional interface modification．The two above problems are studied by focusing on the impregnation theory,molding process and new interface design which comprehensive investigating the impregnation theory and new interface design method． m 万方数据 北京化工大学硕士学位论文The 北京化工大学硕士学位论文 The main focus of the impregnation theory of GFRPP is the viscosity property of the power law fluid flowing in fibrous porous medium．The impregnation model of GFRPP was deduced in this work，the impregnation model is based on Darcy’S law and takes into account the processing parameters and material properties．The impregnation model was validated by a series of experiments，and two kinds of differ