矿物掺合料改善水泥基材料抗硫酸盐侵蚀性能的微观分析-硅酸盐学报.PDF

40 8 1119 40 8 Vol. 40No. 8 2 0 1 2 8 JOURNAL OF THE CHINESE CERAMIC SOCIETY August 2012 1 1 1,2 (1. 211189 2. 210094) CTX 30%50% 5% Na SO 2 a 2 4 C A 3 Al3+ SO2– 4 TU528 A 0454–5648(2012)08–1119–08 2012–07–30 13:23:34 /kcms/detail/11.2310.TQ1323.201208.1119_006.html Effect of Mineral Admixtures on Sulfate Attack Resistance of Cement-Based Materials LI Hua 1 1 1,2 SUN Wei ZUO Xiaobao (1. College of Materials Science and Engineering, Southeast University, Jiangsu Key Laboratory of Construction Materials, Nanjing 211189, China; 2. Department of Civil Engineering, Nanjing University of Science Technology, Nanjing 210094, China) Abstract: The appearance observation, mineral composition, as well as microstructure morphology towards various cement pastes and motars with and without 30% fly ash or 50% slag dipped in 5% Na SO solution at room temperature for 2 years were character- 2 4 ized by X-CT, X-ray diffraction and scanning electron microscopy to investigate the effects of mineral admixtures such as slag and fly ash on the sulfate resistance performance of cement-based materials from the micro-level angle. The results show that the specimens without mineral admixtures appear three different attack states from surface to inside, i.e., the gypsum area, the ettringite area a