粉煤灰煤矸石纤维的软化及其对纸张性能影响的研究化学专业论文.docxVIP

性能的影响。结果表明：将0．25％的CAA与O．6％的BS．12复配，在pH=6 性能的影响。结果表明：将0．25％的CAA与O．6％的BS．12复配，在pH=6 的条件下软化50 rain效果最佳，且当用该复配体系软化过的纤维添加量为 30％时，纸张的抗张强度提高了55．0％，环压强度提高了29．7％；将0．25％ 的CAA与O．15％的CTAB复配，在pH=6的条件下软化60 min效果最佳， 当用该复配体系软化过的纤维添加量为30％时，纸张的抗张强度提高了 45．2％，环压强度提高了25．7％；即在两种复配软化体系中CAA+BS一12复 配体系软化处理纤维效果更好。 (3)粉煤灰／煤矸石纤维的软化增强及复合配抄纸性能的研究 经过软化处理的粉煤灰／煤矸石纤维虽然在一定程度上克服了自身存在 刚性强，脆性大，易断裂的缺点，但软化过的纤维表面基团依然较少，且 纤维表面较光滑，纤维间结合能力不够强，致使复合配抄纸张强度不够理 想。聚乙烯醇．硫酸铝(PVA-A12(S04)3)纤维增强改性剂，是以成膜性优良 的聚乙烯醇(PVA)为原料合成的一种阳离子型纤维改性剂，用其处理纤 维，能在纤维表面形成一层包覆物，有效改善纤维的表面形貌，增强了纤 维间的结合力，进一步提高复合纸的性能。利用BS．12与CAA组成的复配 软化剂及聚乙烯醇一硫酸铝(PVA．A12(S04)3)纤维增强改性剂对其分别进行 软化增强。通过Zeta电位和扫描电镜分析其软化增强效果，并通过粉煤灰／ 煤矸石纤维复合配抄纸张的性能测试，探讨了通过不同方法处理的粉煤灰／ 煤矸石纤维对纸张性能的影响。结果表明将经过处理的粉煤灰／煤矸石纤维 用于造纸，复合纸的性能得到了大幅提高。其中只用CAA+BS．12软化的纤 维加填量为20％，而先用CAA+BS．12处理，再用PVA．A12(804)3软化增强 的纤维加填量为30％时，复合纸的性能可以完全达到纯植物纤维纸张的性 能。 关键词：粉煤灰／煤矸石纤维，造纸，软化剂，纸张性能 II 万方数据 STUDY STUDY ON SOFTENING OF FLY ASH／COAL GANGUE FIBER AND ITS EFFECT oN PAPER PRoPERTIES ABSTRACT This research iS commissioned by the enterprise to soften fly ash／coal gangue fiber which is producted by fly ash，coal gangue that came from the coal combustion．coal washing industry recovered solid waste．In papermaking use the soften fiber,and study its effect on P印er properties．The purpose was to make ny ash／gangue fmer be more suitable for the papermaking industry,in order to achieve the purpose had to do the following three aspects： (1’)Study on softening process of cetyl amino acids fabric soRener(CAA) to fly ash／coal gangue fiber and its effect on Paper properties Fly ash／coal gangue fiber has 1ess surface groups，rigidity,brittleness, easy．breaking．and fibers combining ability is poor．111e composRe paper properties are very poor which directly produced bY fly ash／coal gangue fiber， SO need to soften the舶er and improve the utilization value of the fiber．W油 the cetyrlamine as the main raw material，a kind of amphoteric surfactants was synthesized by carboxylation reaction，it was named that cetyl amino acids fabric softe