超支化环氧的合成及其对dgeba的改性研究材料工程专业论文.docxVIP

北京化工大学硕士学位论文杂环丁烷制备超支化氧杂环丁烷POXEM，并对其结构进行表征。将 北京化工大学硕士学位论文 杂环丁烷制备超支化氧杂环丁烷POXEM，并对其结构进行表征。将 POXEM作为改性剂，添加到E51／_三氟化硼乙胺固化体系中，材料的 Tg提高12。C，冲击性能提高22．8％。 关键词t环氧，超支化聚合物，改性，固化 万方数据 Ab奠ractSYNTHESIS Ab奠ract SYNTHESIS AND APPLICATION oF HYPERBRANCHED PoLYMER WITH EPOXY TERMINAL GROUP ABSTRACT Epoxy materials are widely used in many areas because of their excellent and balanced mechanical，thermal and electrical properties； however,the inadequate toughness limits their application．Epoxy is also used as protective coatings，however its resistances to acid and base as well as cure shrinkage may need to be further improved．In order to address those issues，three hyperbranched polymers were synthesized and used to modify BPA type epoxy,which lead to higll performance epoxy matrix and protective coatings． Using A2+B3 and A2+B4 method，two hyperbranched molecules (HBP3 and HBP4)were synthesized using 1,4-butanediol diglycidyl ether, B3，and B4．Effects of reaction condition，including solvent type， monomer ratio，reaction temperature and time，on molecular weights and its distribution were investigated；and the final product were fully characterized． HBP4 Was added into E5 1／NMA curing system to improve its toughness．Optimum mechanical and thermal properties were achieved at 万方数据 北京化工大学硕士学位论文5wt％loading．The 北京化工大学硕士学位论文 5wt％loading．The tensile strength，impact strength and glass transition temperature(Tg)increase 26．3％，36．4％，and 9．1C，respectively．Several model-free kinetic models were used to evaluate the dynamic cure data and show that addition of HBP4 Can lower activation energy．I-IBP4 Was also successfually introduced into E5 1／NX-2007 coating system without compromising processability,a protective coating，which has much improved film hardness，adhension，impact strength and reisstance to acid and base，Was obtained by spraying． Hyperbranched oxetane (POXElVO Was prepared using 4-fluorophenyl sulfone，trimethylol propane， and 3-methyl一3-oxetanemethanol，and its structure Was characterized．When