14mnnb管线钢生产过程中析出物计算与洁净度研究冶金工程专业论文.docxVIP

AbstractIn Abstract In order to provide the reference for the development of new products via improving the properties of pipeline steel and the control level during the production process furtherly．We analyzed the thermodynamic precipitation conditions of Nb，Ti，A1 as well as MnS in this work based on the regular solution and equilibrium reaction．The conclusions are listed as follows． (1)No precipitation formed in the liquid phase region(T1 79 1 K)because the thermodynamic conditions cannot satisfy the precipitation requirements of carbide，nitride， and MnS in 1 4MnNb pipeline steel． (2)Molten steel enters into the solidification stage(temperature from 1 73 6K to 1791K)and TiN precipitate in 1780K following the decrease of temperature，but other precipitates Can not as the precipitation conditions can not be satisfied． (3)Molten steel solidified(below 1 736K)and transformed into austenite when the temperature decreased continually．Most kinds of precipitate have been seperated out at this stage in the order of MnSNbCTiCA1NNbN．the corresponding precipitation temperature are 1670K，1444K，1357K，1313K，and 1308K，respectively． In addition，we concluded the conclusions based on the analysis for the cleanliness of 1 4MnNb pipeline steel under the production process of EAF--LF··VD··CC by the spectral analysis，infrared analysis，bulk sample electrolysis，image analyzer analysis，scanning electron microscopy,and energy spectrum analysis methods． (1)Roughly，the average amount of oxygen in molten steel exhibits a decrease tendency．Most of the oxygen in molten steel Can be removed in the LF and VD refining process．The oxygen content in 14MnNb steel increased 2．2x 10—6 from the end of VD refining to the tundish process，which indicates that the reoxidation OCCULTS in the transportation and casting stages．The amount of nitrogen in the molten steel shows an increasing trend because the vacuum treatment in VD furnace is beneficial to the Il 万方数据 precipitation precipitation of dissolved nitr