变压吸附空分用酚醛树脂基炭分子筛的制备化学工程与技术专业论文.docxVIP

变压吸附空分用酚醛树脂基炭分子筛的制备Preparation 变压吸附空分用酚醛树脂基炭分子筛的制备 Preparation of Phenol Formaldehyde Resin-based Carbon Molecular Sieves for Air Separation by PSA Abst ract Carbon Molecular Sieves(CMS)，which have the mechanism of molecular sieving，iS a 1(ind of carbonaceous adsorbent with a sharp distribution in micropore range．Similar to the chemical construction of activated carbon，CMS possesses well．developed pore structure and special surface properties．Due to its unique pore structure and selective adsorption of gases of different sized-molecules，CMS iS widely used in gas separation field．Since those qualified CMS should not only high in adsorptive selectivity but also in adsorption capacity,uniformed and appropriate—sized apertures and relatively large pore volumes are further required． Although domestic researches have made some achievements．there are still problems such as low technology process repeatability，poor product performance and deficiencies in the grasp and control of internal mechanisms of critical process step during the preparation process． Taking thermosetting phenolic resin as the raw material，this paper explored the qualitative changes and effects of technological parameter to char in phenolic resin pyrolysis．Instinctive reactions of different products were deduced according to the results drawn from the phase transitions between solid，liquid and gas with the influence of temperature．The changes of grindabilities and pore structures of carbonized materials in various pyrolysis temperatures were inspected and its relations with internal reactions were also covered．Finally,the paper studied and found that the pyrolysis heating rate and granularity of raw materials showed great effect on the varied pore structure of carbonized products． Taking phenolic resin char as raw material and thermosetting phenolic resin as binder，the methods to make CMS Was attempted．During the process．the effect of key processing steps such as usage of binders，carbonization and activa