堆芯灰控制棒用新型中子吸收体铁基复合材料的制备及性能研究核工程与材料专业论文.docxVIP

AbstractAbstract Abstract Abstract China has imported，absorbed and digested the nuclear power technology ofthe AP 1 000 reactor from the American Westinghouse Electric Corporation．In order to create a new type nuclear power technology with our own proprietary intellectual property rights，this article presents correlational research about the neutron absorber material used as the gray rod which is the key material in the core of reactors．On the basis of previous analysies about the burn-up and nucleon character of several elements，we got several candidates，such Tm、Tb and Dy．In this paper，powder metallurgy method(high—energy ball milling，cold Isostatic Pressing and sintering)was used to prepare two kinds of neutron absorber material gray control rod：Fe—Tm203 and Fe—TbFe03一DyFe03 bulks．Material analysis methods were applied to analyze and characterize the microstructure and Micro—chemical dynamics of ball milled powders and sintered bulks．We explored the effects of mi lling process and sintering process on the properties of bulk materials．Plus，the physical properities，mechanical properities and corrosion resistance at high temperature and high pressure of the sintered bulk were tested． The Fe-25．68％Tm203 and Fe-13．19％Tb407—5．81％Dy203 mixed-powder； were processed by high energy ball milling．The XRD analysis result indicated that with the milling time increasing，the diffraction peaks of Tm203，Tb407，Dy203 and Fe will be broadening and the strength will be reducing．Their diffraction peaks were complete ly disappeared after 72h ball milling，and they totally dissolved into the matrix of Fe．No new phases and obvious chemical reaction in the mixed powder were spotted By cold isostatic pressing，the milled powder mixture was made into the green body and then sintered at the range of 600。C to 1 1 00。C．The result showed that Fe reacted with Tm203 and produced the Fe—Tm203 compound．With the sintering time extending，the amount of Tm203 remaining unreacted reduced．After long sinterin