丁腈橡胶耐热改性及其在聚合物基摩擦材料中的应用研究材料学专业论文.docxVIP

AbstractPhenolic Abstract Phenolic resin is popular used in the polymer．matrix friction materials．because it ls supeflor 1n heat reslstance，mechanical propenies，fbming perf．ormance and cost． HoweVer，the ordinary phenolic resins for friction materials have other shortcomings such as a high modulus，hardness and so on，so phenolic resin should be modified． NBR could toughen phenolic resin significantly， but the long chain of nexible elements of N B_R，makes the heat resistance of the friction materiaIs to decline．which I．estrlcts the application in heaVy load，high．speed of the vehicles． So it is ver、r lmportant to modify the NBR to irnprove the features of polymer matrix friction materials． In this papertwo methods are used to modify acrylonitrile-butadiene nlbber there were mainly blending with NBR aIld changing nitrile mbber curing system．The results showed that the two methods were e腑ctive in improving heat resistance of the NBR·The amount of eight percent in blending with PBMI，NBR gets the optimal heat reslstance；the mass is 80％at 500℃，heat resistance of the NBR is improved．In the NBR curing system，when the amount of the curing agent PDM is four，NBR gets the Integrated optlmal perf．omance，and heat resistance is increased significantly， the mass is 50％at 500℃，and heat resistance of the NBR is improved ef．fectively．In the same time，its friction material brake perfo册ance is superior． 1n the experiment， the solution blending compared with the mechanicaI blending of the衔ction material brake perfomance，and the results showed that the solmion blending is superior than mechanical blending blending． Aner that， the solution blending was used to fhrther studv the NBR decentralization in phenolic resin，with the mass ratio of phenolic resin and NBR 1：2， ln whlch heat reslstance agent was introduced in the peroxide curing system of NBR． Ihe results showed that phen01ic resin and NBR mixed for two hours to achieve stability in the solution of acetone，and the panicle diameter of