离子自组装合成侧链型偶氮复合物及其聚集形态研究-ResearchGate.PDF

See discussions, stats, and author profiles for this publication at: /publication/239524300 Study on the Aggregation Morphology of Side-Chain Azocomplex Synthesized by Ionic Self-Assembly Article · January 2010 CITATIONS READS 0 119 1 author: Dequan Xiao University of New Haven 51 PUBLICATIONS   860 CITATIONS    SEE PROFILE Some of the authors of this publication are also working on these related projects: Biomass Catalyst Design, Cancer Drug Discovery, and Polymer Nanostructure Design View project All content following this page was uploaded by Dequan Xiao on 21 May 2014. The user has requested enhancement of the downloaded file. 2010 年第 68 卷 化 学 学 报 Vol. 68, 2010 第 20 期, 2111～2118 ACTA CHIMICA SINICA No. 20, 2111～2118 ·研究论文· 离子自组装合成侧链型偶氮复合物及其聚集形态研究 沙 静 a 林坤华 a 赵永超 a 刘 明 b 江 波 a *,c *,a 肖德泉 殷勤俭 (a 四川大学化学学院 成都 610064) (b 四川大学分析测试中心 成都 610064) (c 耶鲁大学化学系 康奈迪克州纽黑文市 06522) 摘要 用溶液聚合法制备了 4- 乙烯基吡啶与丙烯腈的无规共聚物(P4VP-r-AN), 采用 1H NMR, 13C NMR, DSC 和 FTIR 4 1 等手段确定了其结构和组成. 粘度法测得其粘均分子量为 1.06×10 g/mol, 由其 H NMR 谱峰面积估算得到 4- 乙烯基 吡啶链段的质量百分含量约为 87.1%. 以质子化的 4- 乙