反相微乳法制备均一性水滑石及其在化学发光分析的应用化学工程与技术专业论文.docxVIP

2、采用反相微乳法合成尺寸均一的水滑石纳米材料并用于吸附 2、采用反相微乳法合成尺寸均一的水滑石纳米材料并用于吸附 磺基罗丹明101(S101)染料分子，所建立的S101@LDHs反相微乳 体系能够显著地增敏草酸酯．过氧化氢化学发光体系。通过XRD、 DLS、TEM、UV．vis、荧光偏振以及荧光寿命等手段表征和探究了增 敏机理，并且该体系能够用于检测生物流体中的巯基氨基酸。 关键词：反相微乳，均一『生，水滑石，化学发光 万方数据 ABSTRACTREVERSE ABSTRACT REVERSE MICROEMULSION METHoD MEDIATED SYNTHESIS 0F UNIFo剐M LDHS AND lTS APPLICATIoN IN CHEMILUMINESCENCE ANALY’SIS AB STRACT Chemiluminescence(CL)analysis has been widely investigated because of its outstanding advantages，including high sensitivity，wide linear range，simple equipment and facilitated automation．However，the relatively low CL intensity partially hindered its application in analytical fields．In recent years，nanomaterials amplified CL has attracted growing attention．As a novel synthetic method，reverse microemulsion method has been widely applied to synthesize uniform inorganic nanomaterials with improved property．In this study，we synthesized layered double hydroxides(LDHs)with uniform size distribution via reverse microemulsion method and applied them to catalyze CL reactions．The main werks of this thesis are shown as follows： 1．Using LDHs catalyzed luminol-H202 CL system as a model；we synthesized LDHs in reverse microemulsion with different uniformities and invesitigated the influence of nanomaterial’S tmiformity on CL reactions for the first time．The results indicated the uniformity of LDHs play a vital role on the CL reactions．The LDHs with good uniformity 万方数据 北京化工大学硕士学位论文possessed 北京化工大学硕士学位论文 possessed more catalyze active sites and preferred higher CL intensity． The uniform LDHs catalyzed luminol-H202 CL system could be used as a biosensor for glucose detection in human plasma samples with good reliability。In addition，the uniform LDHs enhanced CL emission was also applicable to other CL systems(P．吕，peroxynitrous acid CL system)． Therefore，the uniform nanomaterial catalyzed CL reactions is universal． 2．We synthesized uniform LDHs in reverse microemulsion for S 1 0 1 dye molecules adsorption，and the resulting