富铅渣的资源化及无害化处理工艺研究化学工艺专业论文.docxVIP

(4)经氯化浸铅、氯化铅回收和铅浸出渣稳定化等过程，可将富铅渣中 (4)经氯化浸铅、氯化铅回收和铅浸出渣稳定化等过程，可将富铅渣中 的铅提取制备为合格的氯化铅产品，有效回收富铅渣中的铅，同时将浸出 渣转变为一般固废，最终实现了富铅渣资源化和无害化处理的目的。 关键词：铅富铅渣氯化浸出 氯化铅资源化稳定化 万方数据 STUDY STUDY ON THE TECHNoLoGY oF RESOURCEFUL UTILIZATIoN AND INNoCENT TREATMENT oF LEAD．IuCH RESIDUE ABSTRACT In the hydrometallurgical extraction process of silver,some by—product of residue，with the lead coutent more than 60％，deposited on the bottom of extraction pot，is one of the hazardous solid waste，which called lead-rich residue．At present，lead—rich residue is stockpiled according to the national standards．However,stockpiling exists serious environmental pollution risks and waste of lead resources in the long-term．In order to improve the utilization of resource，eliminate environmental pollution risks．In this study,calcium chloride leaching··recovery—-cycling·-stabilization process was chosen．The aim is to separate lead from the lead—rich residue，realize the resourceful utilization of residue and conduct stabilization treatment of residual lead，converting it into a general solid waste．The processes of leaching lead with calcium chloride， recovering of lead chloride，recycling of lead leaching solution and stabilization of lead leaching residue were studied in this study,and the results are as follows： (1)In the process of lead leaching with chloride，the optimum conditions were as follows：the mechanical stirring speed was 500 r·min-1，the concentration of chlorine ion was 1 0 mol-L～，the ratio of liquid．solid was 8：1，the reaction temperature was 80。C，the concentration ofhydrochloric acid was 1 mol-L～，the III 万方数据 reaction reaction time was 20 minutes．Influence of chlorine ion concentration and the ratio of liquid to solid on leaching rate of lead were more significant than other factors．Under the above conditions，the leaching rate of lead call reach 93．54％． (2)In the process of lead recovering，the optimum conditions were as follows：the precipitation temperature was 30℃，the precipitation time was 20 min a