代数对芳基苄醚树枝酞菁锌及其聚合物纳米粒子的光物理性质的影响无机化学专业论文.docxVIP

AbstractAbstract Abstract Abstract In this paper,effects of dendrimer generation on intramolecular electron transfer and energy transfer in poly(aryl benzyl ether)dendrietic zinc(II)phthalocyanines with terminal cyano and carboxylic acid functionalities were studied by ultraviolet spectroscopy,steady fluorescence spectrometry and time-resolved fluorescence t口p∥h¨‘一 spectrometry．It was found that，dendritic phthalocyanines wore mainly monomer in common organic solvent．Fluorescence lifetimes and quantum yields of poly(aryl benzyl ether)dendrictic phthalocyanines decreased obviously、Ⅳim an mcrease in the generation． The fluorescence of five dendritic phthalocyanines was quenched by addition of anthraquinone and methyl viologen(MVl through electronic transfer．m‰decreased wim the increase of the generation． Studied on the intramoleeular energy transfer in first and second generation of poly(aryl benzyl ether)dendritic zinc(H)phthalocyanines埘m terminal cyano—group by fluorescence spectroscopy and UV／Vis．The two fluorescence quantum yields(西刚T) were basically consistent through steady fluorescence spectrometry and time·resolved fluorescence spectrometry．The蛳increased wim an increase in the generation．The value of咖ENT for(}2一ZnPc(CN)16 Was determined to be O．88，which meant that these dendritic phthalocyanines were high·efficient light-harvesting system． The interactions of two different surfactants(cetyltrimethyl ammonium bromide (CTAB)and sodium dodccyl sulfle(SDS))and these water-soluble phthalocyanines (ZnPc(COOH)4，GI-ZnPc(COOH)s and G2一ZnPc(COOH)16)were studied．It Was found that,these water-soluble phthalocyanines were mainly monomer with addition of CTAB． We also studied the aggregated behaviors of these water-soluble phthalocyanines varies upon interactions witll CTAB by Zetasize particle size analyzer．The results show mat’ ^母』 average sizes of micelles increased with the increased of the concentration of CTAB．The fluorescence of ZnPc(COOH)4 Was quenched by SDS t