改性炭基吸附剂对烟气中汞的脱除研究化学工艺专业论文.docxVIP

改性炭基吸附剂对烟气中汞的脱除研究Removal 改性炭基吸附剂对烟气中汞的脱除研究 Removal of Elemental Mercury from Flue Gas by Modified Carbon— based Sorbent Abstract Tlle situation that the main energy of China is relied on coal will not be changed in a long time．As a resuk，various pollutants was produced．Wim the increasing awareness of environmental protection and more promulgation ofpolicy，laws and regulations，the pollutants have been controlled．At present，many coal fired plants are equipped with fine particle removal， desulphurization equipment and denitrification facilities，thus dust，SOx and NOx are under contr01．However，the treatment method for heavy metal mercury is not enough．Therefore，it is meaningful to develop a novel efficient cost—effective sorbents for capturing mercury． Petroleum coke is selected as raw material in this study and alkali is employed activation to obtain petroleum coke·based activated carbon(PAC)which is regarded kind of support． Potassium iodide(Ⅺ)or manganese chloride(MnCl2)have been chosen as active materials， and the sorbents were prepared by wet impregnation method and the sorbents were characterized by N2 adsorption，XRD，SEM and FT—IR to analyze the surface properties of sorbents before and after reaction．Experiments were tested in the packed—bed to evaluate the Hgo removal efficiency under different loading values，temperatures and gas components． The results indicated that PAC showed a certain mercury removal performance，but the efficiency decreased wim the increasing temperature．TheⅪimpregnated PAC significantly improved the mercury removal e伍ciency and removal e伍ciency can be increased to above 90％．姗1en the impregnation concentration of KI solution iS 1．5 g／m3 and the mass percent of active component iS 3 wt．％，the sorbent showed better mercury removal performance，and the efficiency showed the trend of increasing in the initial stage and then declined during the temperature of 40—1 20℃。and the best removal efficiency iS at 80℃，the removal efficiency iS above 85％after