杯芳烃的结构修饰及其在离子识别中的应用有机化学专业论文.docxVIP

College College of Chemistry and Chemical Engineering，Yangzhou University,Yangzhou，China Thesis for Master Degree Functional Modification and Application on Ion Recognition of Calixarene Author：Liang Li Supervisor：Ying Han Date：May，2010 Abstract Calixarenes，the third generation supramolecular compound，are more liable to chemical modification．Many kinds of calixarene derivatives with versatile properties can be derived bY modifying the up·rim and the down-rim of the calixarenes．Witll special physical and chemical properties，they have been found versatile applications in number of research fields including molecular recognition,self-assembly,nano materials and catalyst,SO it has been attracted greet interests in home and abroad． Calixarenes modified by heteroatom-containing groups have good complexation and recognization abilities towards heavy metal and transitional metal cations，thus Can be widely used in various fields．In this thesis we have synsized a series of calixarene derivatives containing nitrogen and oxygen atoms，then we also have studied the complexing properties of the prepared functional molecules for transition metal ions． Some meaningful results were obtained． 1．Under the catalysis of concentrated hydrochloric acid，3-methoxyphenol was reacted with aldehyde to form tetramethoxyresorcinarene．The tetrame thoxyres— orcinarene Was alkylated with N··3·-bromopropyl and N--4-bromrobutulphthimide to give tetrasubstituted tetrasubstituted derivatives．Then嘶m reactions of hydrazinolysis，condensation晰th salicylaldehyde，2-pyridinecarboaldehyde sucessefully，a series of calixarene schiff bases were obtained．Their structures were characterized by NMR and IR． 2．Tetramethoxyresorcinarene and resorcinarenes can be efficiently alkylated with chloroacetate to give activated ester derivatives．which in turn were ammonolyzed、^，ith hydrazine or diamines to give hydrazone and amide derivatives．Then the schiff bases could be prepared by the condensated of above hydrazone and am