沸石分子筛的补铝改性及其催化性能研究物理化学专业论文.docxVIP

太原理jf人学硕士研究生学位论文ALUMINATION 太原理jf人学硕士研究生学位论文 ALUMINATION OF ZEOLITE BY NaAl02 SOLUTION AN D THEIR HYDRoGENATION PERFORMANCE ABSTRACT Zeolite USY and Beta are widely used as acid catalysts in the catalytic cracking and dewaxing processes of oil and natural gas as well as aromatic alkylation due to their structural L acid sites resulting from skeleton A1 atoms and B acid sites produced by ion—exchange．As a result，the acid properties of zeolite composite influence the properties of the whole catalyst and consequently have an effect on the catalytic process．Thereby,it is important to modify the acid properties of zeolite composite in the catalyst．In this paper,the acid properties of zeolite USY and Beta were modified with alkaline solution—NaAl02，and the influence of concentration and alkalinity of NaAl02 solution as well as modification time and temperature on the modification process were studied in order to optimize the modification conditions and to improve the acid properties of zeolite．Then，the modified zeolite was chosen as the support of metal Ru catalysts，and their catalytic performances were studied in the liquid—phase benzene hydrogenation reaction． Firstly,series of modified HUSY samples were prepared under various modi fying conditions using NaAl02 solution．These modifying conditions include various modifying time(6h，1 2h，24h)，various modifying IlI 太原理一[：火学硕+研究生学位论文temperature(40。C，60 太原理一[：火学硕+研究生学位论文 temperature(40。C，60 oC，80。C)and NaAl02 solution with various concentration(0．Olmol／L，0．05mol／L，O．1mol／L)and alkalinity(pH=13，pH=14)． The effect of modifying conditions on the acid properties and pore structure of modified HUSY samples were studied by NH3一TPD，IR and Pyridine—IR methods qualitatively and quantitatively．Then，modified HUSY samples were chosen as the support of metal Ru catalysts and their hydrogenation activity were observed in the O．5wt．％benzene／hexane solution．Also，the effect of acid properties of support on the hydrogenation activity of Ru cat