锦纶6Π有机蒙脱土复合纳米纤维的制备与表征-本原扫描探针显微镜.PDF

第 28 卷 　第 11 期 纺 　织 　学 　报 Vol. 28 　No. 11 2007 年 11 月 Journal of Textile Research Nov. 　2007 ( ) 文章编号 2007 锦纶 6有机蒙脱土复合纳米纤维的制备与表征 李琪 ,魏取福 ,汪莹莹 ,王德娟 ,高卫东 (江南大学 生态纺织教育部重点实验室 ,江苏 无锡 　214122) 摘 　要 　通过高压静电纺丝制备锦纶 6有机蒙脱土复合纳米纤维。采用二步插层复合法对有机蒙脱土进行分散 n 和剥离 :先在N ,N二甲基甲酰胺中插层复合 ,然后在锦纶 6 溶液中深层复合。应用纳米粒度分析仪分析有机蒙脱 土片层相对粒径大小和分布范围 ;利用扫描电镜观察并分析纳米纤维的直径、外观 ;运用轻敲模式下的原子力显微 c 镜表征和分析纳米纤维的表面微观结构。结果表明有机蒙脱土加入量对纤维的形态和结构有影响。 关键词 　锦纶 6 ; 有机蒙脱土 ; 复合纳米纤维 ; 形态 ; 结构 . 中图分类号:TQ340. 649 　　　文献标识码 :A 　　　 m Preparation and characterization of PA 6 organical montmorillonite composite nanofibers o LI Qi , WEI Qufu , WANG Yingying , WANG Dejuan , GAO Weidong ( Key Laboratory of Science and Technology of EcoTextiles , Ministry of Education , Jiangnan University , Wuxi , Jiangsu 　214122 , China) c . Abstract 　Composite nanofibers of PA 6 and organically modified montmorillonite (OMMT) , DK5 , were prepared by electrospinning. The dispersion and exfoliation of OMMT were obtained by two steps : the primary exfoliation in DMF and the further exfoliation in PA 6 solution. The size distribution of OMMT layers was m measured in a particle size analyzer and the fibrous structures of the composite nanofiber were examined using SEM. An AFM in tapping mode was employed to investigate the surface morphology of the electrospun nanofibers. The study has rev