低品位锰矿及其改性磁性铁锰复合物对砷ⅲ吸附性能的研究环境科学与工程专业论文.docxVIP

固比为6：1，浸出温度为50。C，浸出时间为2小时，浸出率可达到92．63％。浸 固比为6：1，浸出温度为50。C，浸出时间为2小时，浸出率可达到92．63％。浸 出液中铁锰比为1：1。以四氧化三铁作为磁芯，向浸出液中加入三价铁溶液 使铁锰比达至lJ3：l，经由氢氧化钠和次氯酸钠的沉淀、氧化反应，合成磁性 铁锰复合物。 合成的磁性铁锰复合物是一种无定型的物质，具有Mn—OH、0／．．FeOOH、 Fe．O等基团。在室温下，其具备对中高浓度砷实验水样(0．01mg／LC 0．04mg／L)的吸附能力，具体操作条件为：室温下，吸附剂投加量为0．Ig／L， 溶液pH介于3至7，初始砷浓度为0．4mg／L的实验水样，反应后，砷浓度 可降至0．01mg／L以下。 人工合成的磁性铁锰复合物与天然锰矿相比较，磁性铁锰复合物在提 高砷吸附能力的同时，将除砷的最佳pH值的范围从小于3．3扩宽至3～7的 范围。在将砷浓度降至0．01mg／L的情况下，磁性铁锰复合物投加量是锰矿 的1／10倍，吸附平衡时间缩短l／9倍，能处理的砷初始浓度从0．1mg／L增 大至0．4mg／L，相比而言，磁性铁锰复合物的除砷能力是天然锰矿的50倍。 同时利用磁铁即可轻松实现固液分离，应具有良好的应用前景。 关键词：锰矿砷高温焙烧磁性铁锰复合物吸附机理吸附能力 II 万方数据 THE THE STUDY oF LoW—GRADE MANGANESE oRE AND ITS MoDIFIED MAGNETIC FERRoMANGANESE CoMPoSITE ON ADSORPTION CHARACTERISTICS OF AS(m) ABSTRACT The arsenic pollution in water has been a serious accident in recent years，it is threatening the human health．In this study,manganese ore and its modified magnetic composite ferromanganese were employed to deal with the arsenic in water．A series of physical and chemical experiments were conducted to learn the ore’S adsorption capacity and mechanism on arsenic，and then a modified way on ore WaS explored for beRer adsorption．The divalent manganese ore was leached by an original modified high temperature roasting method．And the leachate WaS used for synthesis of magnetic Fe and Mn complex(MFM for short)． The studies had shown that manganese ore could deal with low arsenic concentration(C0．1mg／L)water,when manganese dosage remained at 1．259／L， the operating conditions were as follow：under 25℃，the initial arsenic concentration was 0．1mg／L，pH value of3．Arsenic concentration in the solution was less than O．Olmg／L after 24h reaction．Fe3+and Ca2+contributed to III 万方数据 adsorption adsorption efficiency,and coexist ion HC03‘in water could reduce the efficiency of adsorption． Adsorption process fitted the Freundlich isotherm model and the pseudo-second order kinetic model；Mn-OH．c【一FeOOH and伐‘Fe203 are the major groups of adsorption．Throughout the adsorption process