半导体纳米氧化亚铜光电催化在含氮农药降解分析中的应用研究化学分析化学专业论文.docxVIP

兰州大学硕士毕业论文 兰州大学硕士毕业论文 张诺 Abstract In this thesis，nanostructures cuprous oxide(cu20)with uniform morphology and appropriate particle size are prepared by wet reduction method at room temperature．The structure，morphologies and characterized of Cu20 nano particle were analyzed by X-ray diffraction(XI①)，Scanning electron microscopy(SEM)and X-ray photoelectron spectroscopy(xPs)．111e electrochemical properties of powers materials were investigated by electrochemical technolo百es，such硒Cyclic Voltammeter(Cv)，Open Circuit Potential(OCP)，Square Wave Voltammetry(SWv)． The promising application and effection in the photocatalytic degradation of pesticide Were discussed by UV—visible spectrophotometer(UV-visible spectrophotometer)at the SalTle time．The main iSSUeS of this thesis were described a_s follows： 1．CUE0 nanoparticles and Sn02 doped CUE0 were synthesized by wet reduction technique．We discussed that Cu20 nanoparticles and Sn02 doped Cu20 their photocatalytic activity in visible light using trifluralin嬲the goal of organic pesticides containing N pollutants．X-ray diffraction(XRD)，scanning electron microscopy (SEM)，X—ray photoelectron spectroscopy(xPs)，Uv—visible spectrophotometer (UV-vis)were used to characterize the morphology and properties of nanoparticles．Results showed that doped and undoped samples were both Cu20 and tlley were octahedral structure，Sn02 doping not only reduced the size of CUE0 particles，but also made them more dispersiver and uniformer．It increaSed the photocatalytic activity of Cu20 and was effective for degradation of trifluralin． 2．Different types(n—type or p-type)of cuprous oxide semiconductor Were prepared with different types of surfactants by wet reduction method．XRD，SEM Were used to characterize the composition and morphology of the materials．The results showed that the nanoparticle materials had uniforill size and were