磁性液体的优化制备及其流变性能的分子动力学模拟固体力学专业论文.docxVIP

摘要关键词：磁性液体流变性能核壳结构微粒分子动力学模拟微观结构 摘要 关键词：磁性液体流变性能核壳结构微粒分子动力学模拟微观结构 ABSTRACTABSTRACT ABSTRACT ABSTRACT Magnetic fluids(Ferrofluids)exhibit a combination of normal liquid behaviors and magnetic controllable properties．Because of their unique physical properties and mechanical performances，magnetic fluids have attracted much attention in wide fields．This research aims to optimize，fabricate，and characterize a new type of magnetic fluids by dispersing Fe@Si02 magnetic particles in a carrier liquid．Both experimental approach and molecular dynamics simulation analysis were conducted to investigate rheological and mechanical properties of magnetic fluids under various working conditions．This research has led to the improvement of antioxidant capacities of magnetic fluids while keeping good magnetoviscous effects of the magnetic fluids． This dissertation firstly reports the optimization and fabrication of magnetic fluids． The olivary core·shell magnetic particles Fe@SiO=，instead of traditionally used Fe304 particles，were synthesized and used for the fabrication of a novel kind of magnetic fluids．The olivary composite particles Fe@Si02 exhibit improved physical and chemical properties because they have both the prominent properties of‘‘core’’ and‘‘shell”components．The amorphous silica“shell’’can effectively inhibit particles aggregation and immunize the encapsulated species against environmental degradation effects while retaining their intrinsic properties．Meanwhile，the nonspherical iron“core”would endow the particles witll magnetic anisotropy character．Rheological properties and viscoelastic behaviors of the fabricated magnetic fluids were characterized with a rheometer．Experimental results showed that this kind of magnetic fluids has a hi曲magnetoviscous effect and a good stability． Their viscoealstic properties are different from the conventional ones because of the particular characters of the functional Fe@Si02 magnetic particles．Additionally,the interaction between t