芳香基硫酚类捕收剂对铅锑锌铁硫化矿捕收性能影响的研究矿物加工工程专业论文.docxVIP

硕士学位论文 硕士学位论文 摘要 摘要 矿产资源目趋贫、细、杂，选别作业难度增加，而随着国民经济 的不断发展，对高品质的矿产原料及有色金属的需求量却不断增加。 如何缓解这一矛盾，实现复杂矿产资源的综合利用，保证国民经济的 可持续发展，已成为当代浮选科技的重大问题之一。脆硫锑铅矿、铁 闪锌矿和黄铁矿是我国铅锑锌铁资源的重要来源，他们之间的分离是 选矿届的热点，开发和寻找新型捕收有着非常重要意义，本文考察了 四种芳香基硫酚捕收剂对这三种矿物的捕收性能影响。 实验结果表明：邻氨基苯硫酚、邻羟基苯硫酚对铁闪锌矿的捕收 效果，明显优于丁黄药，另外两种捕收效果较差；而四种硫酚类捕收 剂，对脆硫锑铅矿的捕收效果都差于丁黄药；另外四种药剂只有在 pH4时，才对黄铁矿有捕收效果。 同时通过红外光谱分析和量子化学计算等方法，探讨了捕收剂与 矿物表面的吸附反应和作用机理。为该方面的进一步研究提供基础的 试验数据。 本研究得到国家自然科学基金重点项目《铅锑铁锌硫化矿选冶基 础研究》和国家自然科学基金项目《利用缓腐蚀效率进行硫化矿捕收 剂结构一活性定量关系研究》的资助。 关键词：邻氨基苯硫酚，邻羟基苯硫酚，邻氟基苯硫酚，对氯邻氨基 苯硫酚，脆硫锑铅矿，铁闪锌矿 硕士学位论文 硕士学位论文 ABSTRACT AB STRACT Witll the mineral resources increasingly deficient，tiny,complicated， their flotation becomes more and more difficult，but the requirement for the mineral raw materials of high quality and nonferrous metals is rising continuously with the development of national economic．How to alleviate the contradiction by carrying out the comprehensive utilization of mineral resources to keep national economic sustainable development has been one of great immediate significance in present flotation scientific and technological fields．Jamesonite、pyrrhotite and marmatite are important Pb、Sb、Zn and Fe mineral resource in China，and the separation of them is hotspot in mineral processing field．SO to empolder and find the new type collectors is very important．In this study,four series of Aryl thiolate collectors ar e used to separate three mineral。 Flotation results show that 2-Amino thiophenol and 2-Hydroxy thiophenol exhibit better Flotation Property than Butyl xanthate for marmatite．And the Flotation Property of the others7 are not very good；For jamesonite the four Aryl thiolate compounds are all worse than Butyl xanthate．And the four Aryl thiolate compounds can collect pyrite when pH4。 The action mechanism and mineral—reagent interaction are discussed according to the result of infrared spectroscopy and computational quantum chemistry．It provi