熔融态钒渣氧化钙化后酸浸研究.pdf

第34卷第5期 钢摇 铁摇 钒摇 钛 Vol郾34,No郾5 2013年10月 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 IRON STEEL VANADIUM TITANIUM 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 October2013 熔融态钒渣氧化钙化后酸浸研究 1,2 1,2 1,2 1,2 李摇 昆 ,宋文臣 ,郑摇 权 ,李摇 宏 (1.北京科技大学 钢铁冶金新技术国家重点实验室,北京100083;2.北京科技大学冶金与生态工程学院,北京100083) 摘摇 要:把钒渣加热到熔融态直接加入CaO并吹氧,将渣中钒氧化为四价或五价与CaO形成钒酸钙,然后酸浸其中 的钒,研究了钙钒比、硫酸浓度和固液比对浸出率的影响。 结果表明:生成以CaV O 为主的钒酸钙盐,在70%钒渣 2 5 粒度小于0.074 mm、钙钒比0.5~0.9、浸出温度90 益、反应时间120 min、固液比1 5颐 、硫酸浓度20%的条件下,钒 浸出率可以达到88%以上。 关键词:熔融态钒渣;钙化焙烧;吹氧;钒酸钙;酸浸 中图分类号:TF841.3;TF803.2 摇 摇 文献标志码:A摇 摇 文章编号:1004-7638(2013)05-0015-04 DOI:10.7513/ j.issn.1004-7638.2013.05.003 Vanadium Extraction by Acid Leaching after Calcification of Molten Vanadium Slag 1,2 1,2 1,2 1,2 Li Kun ,Song Wenchen ,Zheng Quan ,Li Hong (1. State Key Laboratory of Advanced Metallurgy,University of Science andTechnology Beijing,Beijing 100083,Chi鄄 na;2. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083,China) Abstract:Theprocessof extractingvanadiumfrom moltenvanadium slagwassimulated. After vanadium slag was heated to the molten state,CaOwas charged and oxygen wasblown into the slag,by which va鄄 nadium intheslagwasoxidizedintoquadrivalentorpentavalentstateandcalciumvanadatewasobtained. Then acidleachingwasemployedtoextractvanadium. Theinfluenceof calciumtovanadiumratio,sulfu鄄 ric acid concentration and solid-liquid ratio on leaching ratio was investigated. The experiment results show that the calcium vanadate ismainly