炼焦煤中直接添加含铅锌冶金粉尘的焦炉煤气脱硫研究.pdf

第 22 卷第 4 期 环 　境 　科 　学 　学 　报 Vol . 22 ,No . 4 2002 年 7 月 ACTA SCIENTIAE CIRCUMSTANTIAE Jul . ,2002 ( ) 文章编号 2002 　　　中图分类号 :X701. 3 　　　文献标识码 :A 炼焦煤中直接添加含铅锌冶金粉尘的焦炉煤气 脱硫研究 ( 中国科学院过程工 叶树峰 ,郭占成 ,谢裕生 ,唐惠庆 ,赵融芳 ,王开力 , 陈运法　 程研究所 ,北京 　100080) 摘要 :将含铅锌冶金粉尘直接添加到炼焦煤中实现煤气脱硫的新技术 ,使得焦炉煤气脱硫不需要添加专门的脱硫设备成为 可能 ,并可同时完成含铅锌冶金粉尘的回收利用. 研究结果表明,在加入的冶金粉尘中的Zn 和 Pb 的摩尔数与挥发出的硫的 摩尔数之比大于 1 的条件下 ,煤气中的硫可以完全脱除 ,并且焦炭的质量与未加入含铅锌冶金粉尘的没有区别 ,焦炭的收得 率没有降低. 关键词 :含锌铅冶金粉尘 ;焦炉煤气 ;炼焦 ;脱硫剂 ;脱硫 The desulf urization of coke oven gas by adding znic and leadbearing metallurgical dust directly into coking coal YE Shufeng , GUO Zhancheng ,XIE Yusheng ,TANG Huiqing ,ZHAO Rongfang ,WANG Kaili , CHEN Yunfa 　 ( Institute of Process Engineering ,Chinese Academy of Sciences , Beijing 　100080) ( ) ( ) Abstract :A new technology ———desulfurization of coke oven gas COG by adding zinc leadbearing metallurgical dust ZLMD directly into coking coal was developed which makes it possible to avoid special equipment for recycling ZLMD and removal of sulfur in COG. The results showed that the sulfur in coal gas can be completely removed if the molar ratio of the added Zn with Pb to the volatilized S is kept large than 1. The quality of the obtained coke is the same as that without ZLMD added , and in addition , the yield of coke is not reduced after adding ZLMD directly into the mixed coal . ( ) ( ) ( ) Keywords :zinc leadbearing metallurgical dust ZLMD ; coke oven gas COG ; coking ; sulfur sorbent S