用热分析法研究木材阻燃剂FRW的阻燃机理.pdf

24 3 Vol. 24 No. 3 2004 9 Chemistry and Industry of Forest Products Sept. 2004 FRW 王清文, 李 坚 ( 东北林业大学木材科学与技术研究所, 黑龙江 哈尔滨 150040) WANG Q W : (T G)(DTG) ( DTA) , FRW ( GUP) ( BZ) GUP (GZ)FRW ( FZ) (UZ)TG DTG , FRW , : 95 160 ,GUP 180285 385 (GPP)(APP) ( PPA) FRW , , , BZ ( 165 ) , ( ) ;GUP 375 (UZ) 314 ( GZ) , ,;FZ ,TG , FZ BZ GZ , 3,GUP DTA , BZ DTA 425 , : ; FRW; ; :TQ314. 248 :A :0253- 2417( 2004) 03- 0037- 05 STUD ON FIRE-RETARDATION MECHANISM OF FIRE RETARDANT FRW B THERMOANAL SIS WANG Qing-wen, LI Jian ( Resear ch I nsti tute of Wood Scie nce and Tech nol ogy , N or theast Forest ry Univ ers ity , H ar bi n 150040, Chi na) Abstract: The thermo-decomposition of fire retardant FRW and its main components,namely boric acid and guany- lurea phosphate( GUP) , and the pyrolysis of basswood treated with boric acid( BZ) , basswood treated with GUP ( GZ) ,basswood treated with FRW( FZ) and untreated basswood( UZ) were analyzed by thermogravimetry( TG and DT G) and differential thermoanalysis( DTA) respectively.T he TG and DTG results revealed that when fire retar- dant FRW was heated to its decomposition temperature its components decomposed independently, thus boric acid decomposed to HBO ( at about 95 ) , the later in turn to B O ( at about 160 ) . GUP decomposed to guanidine 2 2 3 polyphosphate GPP( at about 180 ) , then to ammonium polyphosphate APP( at about 285 ) , and in turn to :2003- 12- 29 :( : ( 1961- ) , , , , , ; E-mail:qwwa