由弹性键连接的V形分子双轴向列相液晶的相变.pdf

33 2 () Vol. 33 No. 2 2010 6 JOURNAL OF NANJING NORMAL UNIVERSITY ( Natural Science Edition) Jun, 2010 由弹性键连接的V 形分子双轴向列相液晶的相变 翟雪雅, 刘 红 (, 210097) [ ] V . , , . k r. k 0 k 0 |k | r, , ; k 0, r 1 |k | , , , |k |, , . k 0 |k | r = 1 , , |k |, , . [ ] , , [ ] O56; O572. 24 [] A [] 1001-4616( 2010) 02-0031-07 BiaxialNematic Liquid CrystalPhase Transition of V-ShapedMolecules Connected by FlexibleChain Z ha i Xueya, L iu Hong ( School of Ph sics and Technolog , Nanjing Norm alU niversit, N anjing 210097, Ch ina) bstract:The phase transitions in V-shaped m olecular s stem where the wt om olecu lar arm s are connected b a flex ible chain are stud ied. Based on a smi ple interaction energ bewt een molecu les and the approx mi ation ofm ean-field theor , order param eters of equ ilibrium state as functions of reduced temperature, and phase diagram s in the p lane ofm olecu lar structure and temperature are obtained. The resu lts show that the phase transition temperatures are related to the elastic strength of flex ible chain k and ratio of tw o arm s length r. When k 0, or k 0 but |k | r, as the tem perature decrea- ses, s stem undergoes a first order transition from isotrop ic phase to un iax ial phase. W hen k 0, r 1 and |k | r, s s- tem has a first order phase trans ition from isotrop ic to uniax ial phase, then a second order phase transition from un iax ial to biax ial phase. When |k | continues to increase, the first orderw ill change into aw eak first order or a con tinuous tran- s ition. When k 0