通过原子转移自由基聚合对聚氯乙烯进行化学改性.PDF

6 /20024 Chemical Modification of Polyvinyl Chloride v ia Atom T ransfer Radical Polymerization Process , (, 100081) WAN Wen-jun, DON Yu-ping (School of Chemical Engineering Material Science, Beijing Institute of Technology Beijing, 100081, China) : ( BMA) (PVC) , PVC-g-PBMAPVC , PVC-g-PBMA, PBMA PVCDSC : PVC-g-PBMA Tg , PBMA , : ; ; ; : T Q325. 3; TB324: A: 1001-4381 (2002) 04-0006-03 Abstract : raft copolymers of poly (vinyl chloride) with butyl methacrylate were successfully syn- thesized v ia AT RP Atom Transfer Radical Polymerization process Compared with the previous( ) . ones the most obvious advantage of the above process was that through which there existed only, graft copolymers in the consequent product without either BMA homopolymers or PVC T hermal, . ( ) g . g analysis DSC revealed only one T for all copolymers T he T of graft copolymers decreased with increasing content of butyl methacrylate which indicated that the toughness of the copolymers in-, creased gradually. Key words: polyvinyl chloride chemical modification atom transfer radical polymerization butyl; ; ; methacrylate (PVC) , PVC , : , PVC , , , PVC (Atom , PVC , Transfer Radical Polymerization, ATRP) PVC , , , PVC , , , [ 1] 1995 , ( [2] ) , : ; PVC PVC (Initiation) n n+ 1 R-Cl+ Mt Lx R + Mt Lx , k +