锐钛矿制备钛硅分子筛ETS.pdf

第32 卷第9期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol32, No. 9 2 0 1 1 年 9 月 Journal of Northeastern U ni ersity( Natural Science) Sep. 2 0 1 1 ETS- 10 1 2 1 1, 3 刘丽影 , 覃文军, 翟玉春, 徐 冬 ( 1. , 110819; 2. , 110819; 3. , 3800) : , , ET S - 10 , XRD- ET S- 10 , ET S- 10 , , , 2 3 , 07 nm, BET , 333 m / g 02 1cm / g ET S- 10 , CO , CH N ET S- 10 , 2 4 2 CO / N , CO 2 2 2 : ; ET S- 10; ; ; : T B 383 : A : 1005-3026( 2011) 09- 1278-04 Synthesis and Characterization of Titanium Silicalite Zeolite ETS-10 Using Anatase 1 2 1 1, 3 L I U L i-ying , TA N Wen-j un , ZHA I Yu-chun , X U Dong ( 1. School of Materials Metallurgy , Northeastern Uni ersity, Shenyang 110819, China; 2. Research Academy, Northeastern Uni ersity, Shenyang 110819, China; 3. School of Engineering, Monash Uni ersity, Melbourn 3800, Australia. Corresponding aut hor: LIU L-i y ing , E-mail: liuqi18576 @ 126. com) Abstract: The synthesis process of titanium silicalite zeolite ET S- 10 using commercial anatase and Na SiO w ithout the addition of fluoride ions was in estigated. T he synthesized ETS- 10 was 2 3 characterized by X-ray diffraction, scanning electron microscopy, thermogra imetric and N2 adsorption-desorption. T he results show ed that the prepared ET S- 10 exhibits high BET surface 2 3 area and pore olume of 333 m / g and 021 cm / g